Projects funded by the NCN

Information on the principal investigator and host institution

Information of the project and the call

Keywords

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New catalytic methods for the synthesis of functionalized silsesquioxanes via coupling reactions and further modification of obtained products

2017/27/N/ST5/00091

Keywords:

silsesquioxanes POSS silanols hydrosilylation

Descriptors:

  • ST5_18:
  • ST5_24:

Panel:

ST5 - Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution :

Uniwersytet im. Adama Mickiewicza w Poznaniu, Wydział Chemii

woj. wielkopolskie

Other projects carried out by the institution 

Principal investigator (from the host institution):

Joanna Kaźmierczak 

Number of co-investigators in the project: 2

Call: PRELUDIUM 14 - announced on 2017-09-15

Amount awarded: 209 200 PLN

Project start date (Y-m-d): 2018-08-03

Project end date (Y-m-d): 2021-08-02

Project duration:: 36 months (the same as in the proposal)

Project status: Project settled

Project description

Download the project description in a pdf file

Note - project descriptions were prepared by the authors of the applications themselves and placed in the system in an unchanged form.

Equipment purchased [PL]

  1. Pompa próżniowa.
  2. Lodówka laboratoryjna (8 000 PLN)
  3. Myjka ultradźwiękowa z regulowaną mocą z systemem zmiany częstotliwosci (4 000 PLN)
  4. Zestaw komputerowy (10 000 PLN)
  5. Mieszadło magnetyczne z elektronicznym termometrem (2 szt.) (8 000 PLN)

Information in the final report

  • Publication in academic press/journals (3)
  • Articles in post-conference publications (1)
  1. B(C6F5)3‑Catalyzed Dehydrocoupling of POSS Silanols with Hydrosilanes: A Metal-Free Strategy for Effecting Functionalization of Silsesquioxanes
    Authors:
    Joanna Kaźmierczak, Dariusz Lewandowski, Grzegorz Hreczycho
    Academic press:
    Inorganic Chemistry (rok: 2020, tom: 59, strony: 9206-9214), Wydawca: ACS
    Status:
    Published
    DOI:
    10.1021/acs.inorgchem.0c01125 - link to the publication
  2. Highly effective functionalization of silsesquioxanes mediated by inexpensive earth-abundant metal catalyst – Potassium tert-butoxide
    Authors:
    Joanna Kaźmierczak, Grzegorz Hreczycho
    Academic press:
    Journal of Catalysis (rok: 2019, tom: 378, strony: 90-96), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.jcat.2019.08.022 - link to the publication
  3. Ru-Catalyzed Dehydrogenative Silylation of POSS-Silanols with Hydrosilanes: Its Introduction to One-Pot Synthesis
    Authors:
    Joanna Kaźmierczak, Krzysztof Kuciński,*Dariusz Lewandowski, Grzegorz Hreczycho
    Academic press:
    Inorganic Chemistry (rok: 2019, tom: 58, strony: 1201-1207), Wydawca: ACS
    Status:
    Published
    DOI:
    10.1021/acs.inorgchem.8b02645 - link to the publication
  1. Novel catalytic methodologies for the synthesis of functionalized silsesquioxanes
    Authors:
    Joanna Kaźmierczak. Grzegorz Hreczycho
    Conference:
    International Conference On Phosphorus, Boron and Silicon – PBSi 2019 (rok: 2019, ), Wydawca: Prem C
    Data:
    konferencja 2019-12-02 - 2019-12-04
    Status:
    Published

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