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From novel rhenium(I) complexes with triimine ligands towards more efficient photo- and electroluminescence materials

2017/25/B/ST5/01611

Keywords:

rhenium(I) carbonyls triimine ligands photoluminescence electroluminescence optoelectronics

Descriptors:

  • ST5_14: Other related subjects
  • ST5_4: Thin films
  • ST5_23:

Panel:

ST5 - Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution :

Uniwersytet Śląski w Katowicach, Wydział Nauk Ścisłych i Technicznych

woj. śląskie

Other projects carried out by the institution 

Principal investigator (from the host institution):

prof. Barbara Machura 

Number of co-investigators in the project: 13

Call: OPUS 13 - announced on 2017-03-15

Amount awarded: 906 330 PLN

Project start date (Y-m-d): 2018-01-26

Project end date (Y-m-d): 2021-07-25

Project duration:: 42 months (the same as in the proposal)

Project status: Project settled

Project description

Download the project description in a pdf file

Note - project descriptions were prepared by the authors of the applications themselves and placed in the system in an unchanged form.

Equipment purchased [PL]

  1. zestaw komputerowy z systemem (4 150 PLN)
  2. chłodziarka do czterokołowego dyfraktometru rentgenowskiego (60 000 PLN)
  3. molibdenowa lampa rentgenowska (37 000 PLN)
  4. wyparka z pompą próżniową (32 000 PLN)
  5. lampa (oświetlacz) ksenonowy.
  6. miernik mocy optycznej (8 699 PLN)
  7. profilomierz wiązki laserowej (26 173 PLN)
  8. waga (12 000 PLN)
  9. potencjostat.

Information in the final report

  • Publication in academic press/journals (13)
  1. Optical properties of 2,6-di(pyrazin-2-yl)pyridines substituted with extended aryl groups
    Authors:
    M. Małecka, B. Machura, A. Szlapa-Kula
    Academic press:
    Dyes and Pigments, 2021, 188, 109168 (rok: 2021, tom: 188, strony: 109168), Wydawca: Elsevier Ltd.
    Status:
    Published
    DOI:
    10.1016/j.dyepig.2021.109168 - link to the publication
  2. Tuning Optical Properties of Re(I) Carbonyl Complexes by Modifying Push-Pull Ligands Structure
    Authors:
    T. Klemens, A. Świtlicka, A. Szlapa-Kula, Ł. Łapok, M. Obłoza, M. Siwy M. Szalkowski S. Maćkowski, M. Libera, E. Schab-Balcerzak, B. Machura
    Academic press:
    Organometallics (rok: 2019, tom: 38, strony: 4206-4223), Wydawca: ACS Publications
    Status:
    Published
    DOI:
    10.1021/acs.organomet.9b00517 - link to the publication
  3. Ground- and excited-state properties of Re(I) carbonyl complexes - effect of triimine ligand core and appended heteroaromatic groups,
    Authors:
    K. Choroba, S. Kotowicz, A. Maroń, A. Świtlicka, A. Szłapa-Kula, M. Siwy, J. Grzelak, K. Sulowska, S. Maćkowski, E. Schab-Balcerzak, B. Machura
    Academic press:
    Dyes and Pigments, (rok: 2021, tom: 192, strony: 109472), Wydawca: Elsevier Ltd.
    Status:
    Published
    DOI:
    10.1016/j.dyepig.2021.109472 - link to the publication
  4. A family of solution processable ligands and their Re(I) complexes towards light emitting applications
    Authors:
    T. Klemens, A. Świtlicka, B. Machura, S. Kula, S. Krompiec, K. Łaba, M. Korzec,M. Siwy, H. Janeczek, E. Schab-Balcerzak, M. Szalkowski, J. Grzelak, S. Maćkowski
    Academic press:
    Dyes and Pigments (rok: 2019, tom: 163, strony: 89-101), Wydawca: Elsevier Ltd.
    Status:
    Published
    DOI:
    10.1016/j.dyepig.2018.11.035 - link to the publication
  5. Insight into structure-property relationships of aryl-substituted 2,2′:6′,2″-terpyridines
    Authors:
    A. Szlapa-Kula, M. Małecka, B. Machura
    Academic press:
    Dyes and Pigments (rok: 2020, tom: 180, strony: 108480), Wydawca: Elsevier Ltd.
    Status:
    Published
    DOI:
    10.1016/j.dyepig.2020.108480 - link to the publication
  6. Aryl substituted 2,6-di(thiazol-2-yl)pyridines - excited-state characterization and potential for OLEDs
    Authors:
    K. Choroba, S. Kula, A. Maroń, B. Machura, J. Małecki, A. Szłapa-Kula, M. Siwy, J. Grzelak, S. Maćkowski, E. Schab-Balcerzak
    Academic press:
    Dyes and Pigments (rok: 2019, tom: 169, strony: 89-104), Wydawca: Elsevier Ltd.
    Status:
    Published
    DOI:
    10.1016/j.dyepig.2019.05.015 - link to the publication
  7. Experimental and computational exploration of photophysical and electroluminescent properties of modified 2,2′:6′,2″-terpyridine, 2,6-di(thiazol-2-yl)pyridine and 2,6-di(pyrazin-2-yl)pyridine ligands and their Re(I) complexes
    Authors:
    T. Klemens, A. Świtlicka, A. Szlapa-Kula, S. Krompiec, P. Lodowski, A. Chrobok, M. Godlewska, S. Kotowicz, M. Siwy, K. Bednarczyk, M. Libera, S. Maćkowski, T. Pędziński, E. Schab-Balcerzak, B. Machura
    Academic press:
    Applied Organometallic Chemistry (rok: 2018, tom: 32, strony: e4611), Wydawca: John Wiley & Sons, Ltd.
    Status:
    Published
    DOI:
    10.1002/aoc.4611 - link to the publication
  8. In-depth studies of ground- and excited-state properties of Re(I) carbonyl complexes bearing 2,2′:6′,2′′-terpyridine and 2,6-bis(pyrazin-2-yl)pyridine coupled with π-conjugated aryl chromophores
    Authors:
    Agata Szlapa-Kula , Magdalena Małecka , Anna Maroń , Henryk Janeczek, Mariola Siwy, Ewa Schab-Balcerzak, Marcin Szalkowski, Sebastian Maćkowski, Tomasz Pedzinski, Karol Erfurt, Barbara Machura
    Academic press:
    Inorganic Chemistry , Wydawca: ACS Publications
    Status:
    Accepted for publication
    DOI:
    10.1021/acs.inorgchem.1c02151 - link to the publication
  9. Carbazole effect on ground- and excited-state properties of rhenium(i) carbonyl complexes with extended terpy-like ligands
    Authors:
    K. Choroba, A. Maroń, A. Świtlicka, A. Szłapa-Kula, M. Siwy, J. Grzelak, S. Maćkowski, T. Pedzinski, E. Schab-Balcerzak, B. Machura
    Academic press:
    Dalton Transactions (rok: 2021, tom: 50, strony: 3943-3958), Wydawca: RSC Publishing
    Status:
    Published
    DOI:
    10.1039/D0DT04340K - link to the publication
  10. Photoluminescence enhancement of Re(I) carbonyl complexes bearing D-A and D-π-A ligands
    Authors:
    A. M. Maroń, A. Szłapa-Kula, M. Matussek, R. Kruszyński, M. Siwy, H. Janeczek, J. Grzelak, S. Mackowski, E. Schab-Balcerzak, B. Machura
    Academic press:
    Dalton Transactions (rok: 2020, tom: 49, strony: 4441-4453), Wydawca: RSC
    Status:
    Published
    DOI:
    10.1039/C9DT04871E - link to the publication
  11. Structure-dependent and environment-responsive optical properties of the trisheterocyclic systems with electron donating amino groups
    Authors:
    J. Palion-Gazda, B. Machura, T. Klemens, A. Szlapa-Kula, S. Krompiec, M. Siwy, H. Janeczek, E. Schab-Balcerzak. J. Grzelak, S. Maćkowski
    Academic press:
    Dyes and Pigments (rok: 2019, tom: 166, strony: 283-300), Wydawca: Elsevier Ltd.
    Status:
    Published
    DOI:
    10.1016/j.dyepig.2019.03.035 - link to the publication
  12. The effect of 2-, 3- and 4-pyridyl substituents on photophysics of fac-[ReCl (CO)3(n-pytpy-κ2N)] complexes: Experimental and theoretical insights
    Authors:
    T. Klemens, A. Świtlicka, S. Kula, M. Siwy, K. Łaba, J. Grzelak, M. Szalkowski, S. Maćkowski, E. Schab-Balcerzaka, B. Machura
    Academic press:
    Journal of Luminescence (rok: 2019, tom: 209, strony: 346-356), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.jlumin.2019.01.045 - link to the publication
  13. Towards better understanding of photophysical properties of rhenium(I) tricarbonyl complexes with terpy-like ligands
    Authors:
    M. Małecka, B. Machura, A. Świtlicka, S. Kotowicz, G. Szafraniec-Gorol,M. Siwy, M. Szalkowski, S. Maćkowski, E. Schab-Balcerzak
    Academic press:
    Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy (rok: 2020, tom: 231, strony: 118124), Wydawca: Elsevier Ltd.
    Status:
    Published
    DOI:
    10.1016/j.saa.2020.118124 - link to the publication

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