From novel rhenium(I) complexes with triimine ligands towards more efficient photo- and electroluminescence materials

2017/25/B/ST5/01611

Keywords

Descriptors

  • ST5_14: Chemia koordynacyjna
  • ST5_4: Cienkie warstwy
  • ST5_23: Chemia organiczna

Panel

ST5 – Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution

UNIWERSYTET ŚLĄSKI, Wydział Nauk Ścisłych i Technicznych

Voivodeship: śląskie

Other projects carried out by the institution »

Principal investigator (from the host institution)

prof. Barbara Elżbieta Machura

Number of co-investigators in the project: 13

Call

OPUS 13 – announced on 2017-03-15

Amount awarded
906 330 PLN
Project start date
2018-01-26
Project end date
2021-07-25
Project duration
42 months (the same as in the proposal)
Project status
Project settled

Project description

Download the project description in a pdf file

Note — project descriptions were prepared by the authors of the applications themselves and placed in the system in an unchanged form.

Equipment purchased [PL]

  1. chłodziarka do czterokołowego dyfraktometru rentgenowskiego. Cost: 60 000 PLN
  2. lampa (oświetlacz) ksenonowy.
  3. miernik mocy optycznej. Cost: 8 699 PLN
  4. molibdenowa lampa rentgenowska. Cost: 37 000 PLN
  5. potencjostat.
  6. profilomierz wiązki laserowej. Cost: 26 173 PLN
  7. waga. Cost: 12 000 PLN
  8. wyparka z pompą próżniową. Cost: 32 000 PLN
  9. zestaw komputerowy z systemem. Cost: 4 150 PLN

Information in the final report

Publication in academic press/journals (13)

  1. Tuning Optical Properties of Re(I) Carbonyl Complexes by Modifying Push-Pull Ligands Structure

    Authors:
    T. Klemens, A. Świtlicka, A. Szlapa-Kula, Ł. Łapok, M. Obłoza, M. Siwy M. Szalkowski S. Maćkowski, M. Libera, E. Schab-Balcerzak, B. Machura
    Academic press:
    Organometallics (year: 2019, volume: 38, pages: 4206-4223), Publisher: ACS Publications
    Status:
    Published
    DOI:
    10.1021/acs.organomet.9b00517 – link to the publication
  2. Aryl substituted 2,6-di(thiazol-2-yl)pyridines - excited-state characterization and potential for OLEDs

    Authors:
    K. Choroba, S. Kula, A. Maroń, B. Machura, J. Małecki, A. Szłapa-Kula, M. Siwy, J. Grzelak, S. Maćkowski, E. Schab-Balcerzak
    Academic press:
    Dyes and Pigments (year: 2019, volume: 169, pages: 89-104), Publisher: Elsevier Ltd.
    Status:
    Published
    DOI:
    10.1016/j.dyepig.2019.05.015 – link to the publication
  3. The effect of 2-, 3- and 4-pyridyl substituents on photophysics of fac-[ReCl (CO)3(n-pytpy-κ2N)] complexes: Experimental and theoretical insights

    Authors:
    T. Klemens, A. Świtlicka, S. Kula, M. Siwy, K. Łaba, J. Grzelak, M. Szalkowski, S. Maćkowski, E. Schab-Balcerzaka, B. Machura
    Academic press:
    Journal of Luminescence (year: 2019, volume: 209, pages: 346-356), Publisher: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.jlumin.2019.01.045 – link to the publication
  4. Structure-dependent and environment-responsive optical properties of the trisheterocyclic systems with electron donating amino groups

    Authors:
    J. Palion-Gazda, B. Machura, T. Klemens, A. Szlapa-Kula, S. Krompiec, M. Siwy, H. Janeczek, E. Schab-Balcerzak. J. Grzelak, S. Maćkowski
    Academic press:
    Dyes and Pigments (year: 2019, volume: 166, pages: 283-300), Publisher: Elsevier Ltd.
    Status:
    Published
    DOI:
    10.1016/j.dyepig.2019.03.035 – link to the publication
  5. Carbazole effect on ground- and excited-state properties of rhenium(i) carbonyl complexes with extended terpy-like ligands

    Authors:
    K. Choroba, A. Maroń, A. Świtlicka, A. Szłapa-Kula, M. Siwy, J. Grzelak, S. Maćkowski, T. Pedzinski, E. Schab-Balcerzak, B. Machura
    Academic press:
    Dalton Transactions (year: 2021, volume: 50, pages: 3943-3958), Publisher: RSC Publishing
    Status:
    Published
    DOI:
    10.1039/D0DT04340K – link to the publication
  6. Ground- and excited-state properties of Re(I) carbonyl complexes - effect of triimine ligand core and appended heteroaromatic groups,

    Authors:
    K. Choroba, S. Kotowicz, A. Maroń, A. Świtlicka, A. Szłapa-Kula, M. Siwy, J. Grzelak, K. Sulowska, S. Maćkowski, E. Schab-Balcerzak, B. Machura
    Academic press:
    Dyes and Pigments, (year: 2021, volume: 192, pages: 109472), Publisher: Elsevier Ltd.
    Status:
    Published
    DOI:
    10.1016/j.dyepig.2021.109472 – link to the publication
  7. A family of solution processable ligands and their Re(I) complexes towards light emitting applications

    Authors:
    T. Klemens, A. Świtlicka, B. Machura, S. Kula, S. Krompiec, K. Łaba, M. Korzec,M. Siwy, H. Janeczek, E. Schab-Balcerzak, M. Szalkowski, J. Grzelak, S. Maćkowski
    Academic press:
    Dyes and Pigments (year: 2019, volume: 163, pages: 89-101), Publisher: Elsevier Ltd.
    Status:
    Published
    DOI:
    10.1016/j.dyepig.2018.11.035 – link to the publication
  8. Experimental and computational exploration of photophysical and electroluminescent properties of modified 2,2′:6′,2″-terpyridine, 2,6-di(thiazol-2-yl)pyridine and 2,6-di(pyrazin-2-yl)pyridine ligands and their Re(I) complexes

    Authors:
    T. Klemens, A. Świtlicka, A. Szlapa-Kula, S. Krompiec, P. Lodowski, A. Chrobok, M. Godlewska, S. Kotowicz, M. Siwy, K. Bednarczyk, M. Libera, S. Maćkowski, T. Pędziński, E. Schab-Balcerzak, B. Machura
    Academic press:
    Applied Organometallic Chemistry (year: 2018, volume: 32, pages: e4611), Publisher: John Wiley & Sons, Ltd.
    Status:
    Published
    DOI:
    10.1002/aoc.4611 – link to the publication
  9. Insight into structure-property relationships of aryl-substituted 2,2′:6′,2″-terpyridines

    Authors:
    A. Szlapa-Kula, M. Małecka, B. Machura
    Academic press:
    Dyes and Pigments (year: 2020, volume: 180, pages: 108480), Publisher: Elsevier Ltd.
    Status:
    Published
    DOI:
    10.1016/j.dyepig.2020.108480 – link to the publication
  10. Photoluminescence enhancement of Re(I) carbonyl complexes bearing D-A and D-π-A ligands

    Authors:
    A. M. Maroń, A. Szłapa-Kula, M. Matussek, R. Kruszyński, M. Siwy, H. Janeczek, J. Grzelak, S. Mackowski, E. Schab-Balcerzak, B. Machura
    Academic press:
    Dalton Transactions (year: 2020, volume: 49, pages: 4441-4453), Publisher: RSC
    Status:
    Published
    DOI:
    10.1039/C9DT04871E – link to the publication
  11. Towards better understanding of photophysical properties of rhenium(I) tricarbonyl complexes with terpy-like ligands

    Authors:
    M. Małecka, B. Machura, A. Świtlicka, S. Kotowicz, G. Szafraniec-Gorol,M. Siwy, M. Szalkowski, S. Maćkowski, E. Schab-Balcerzak
    Academic press:
    Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy (year: 2020, volume: 231, pages: 118124), Publisher: Elsevier Ltd.
    Status:
    Published
    DOI:
    10.1016/j.saa.2020.118124 – link to the publication
  12. Optical properties of 2,6-di(pyrazin-2-yl)pyridines substituted with extended aryl groups

    Authors:
    M. Małecka, B. Machura, A. Szlapa-Kula
    Academic press:
    Dyes and Pigments, 2021, 188, 109168 (year: 2021, volume: 188, pages: 109168), Publisher: Elsevier Ltd.
    Status:
    Published
    DOI:
    10.1016/j.dyepig.2021.109168 – link to the publication
  13. In-depth studies of ground- and excited-state properties of Re(I) carbonyl complexes bearing 2,2′:6′,2′′-terpyridine and 2,6-bis(pyrazin-2-yl)pyridine coupled with π-conjugated aryl chromophores

    Authors:
    Agata Szlapa-Kula , Magdalena Małecka , Anna Maroń , Henryk Janeczek, Mariola Siwy, Ewa Schab-Balcerzak, Marcin Szalkowski, Sebastian Maćkowski, Tomasz Pedzinski, Karol Erfurt, Barbara Machura
    Status:
    Accepted for publication

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Graphic design and implementation: Jakub Piotrowski