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Information on the principal investigator and host institution

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Keywords

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Multinuclear metal complexes with large macrocycles derived from 2,6-diformylpyridine and trans-1,2-diaminocyclopentane.

2017/25/B/ST5/00722

Keywords:

macrocycle complex multinuclear chirality

Descriptors:

  • ST5_22:
  • ST5_24:
  • ST5_14: Other related subjects

Panel:

ST5 - Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution :

Uniwersytet Wrocławski, Wydział Chemii

woj. dolnośląskie

Other projects carried out by the institution 

Principal investigator (from the host institution):

dr Janusz Gregoliński 

Number of co-investigators in the project: 5

Call: OPUS 13 - announced on 2017-03-15

Amount awarded: 533 300 PLN

Project start date (Y-m-d): 2018-01-12

Project end date (Y-m-d): 2022-01-11

Project duration:: 48 months (the same as in the proposal)

Project status: Project settled

Project description

Download the project description in a pdf file

Note - project descriptions were prepared by the authors of the applications themselves and placed in the system in an unchanged form.

Equipment purchased [PL]

  1. Zawór do przełączania kolumn GPC (4 500 PLN)
  2. mieszadło magnetyczne (7 000 PLN)
  3. System próżniowy z kontrolą ciśnienia (20 000 PLN)
  4. Wyparka próżniowa (14 000 PLN)
  5. Kolumna preparatywna do chromatografii GPC (52 000 PLN)
  6. Zestaw do woltamperometrii cyklicznej. (90 000 PLN)
  7. myjka ultradźwiękowa.
  8. zbiornik Devara (7 000 PLN)

Information in the final report

  • Publication in academic press/journals (5)
  1. Mixed macrocycles derived from 2,6-diformylpyridine and opposite enantiomers of trans-1,2-diaminocyclopentane and trans-1,2-diaminocyclohexane.
    Authors:
    Rafał Frydrych, Katarzyna Ślepokura, Andrzej Bil, Janusz Gregoliński
    Academic press:
    Journal of Organic Chemistry (rok: 2019, tom: 84, strony: 5695−5711), Wydawca: ACS
    Status:
    Published
    DOI:
    10.1021/acs.joc.9b00614 - link to the publication
  2. Multinuclear Ni(II) and Cu(II) complexes of meso 6+6 macrocyclic amine derived from trans-1,2-diaminocyclopentane and 2,6-diformylpyridine
    Authors:
    Janusz Gregoliński, Katarzyna Ślepokura, Julia Kłak, Maciej Witwicki
    Academic press:
    Dalton Transactions , Wydawca: Royal Society of Chemistry
    Status:
    Submitted
    DOI:
    brak - link to the publication
  3. A New Synthetic Strategy Leading to Homochiral Macrocycles Derived from 2,6-Diformylpyridine and (1S,2S)-trans-1,2- Diaminocyclopentane
    Authors:
    Janusz Gregoliński, Katarzyna Ślepokura, Andrzej Bil, Jerzy Lisowski
    Academic press:
    European Journal of Organic Chemistry (rok: 2020, tom: 35, strony: 5714-5728), Wydawca: Wiley-VCH GmbH
    Status:
    Published
    DOI:
    10.1002/ejoc.202000919 - link to the publication
  4. Controlling chirality in the synthesis of 4 + 4 diastereomeric amine macrocycles derived from trans-1,2-diaminocyclopentane and 2,6- diformylpyridine
    Authors:
    Dominika Fedorowicz, Sylwia Banach, Patrycja Koza, Rafał Frydrych, Katarzyna Ślepokura Janusz Gregoliński
    Academic press:
    Organic & Biomolecular Chemistry (rok: 2022, tom: 20, strony: 1080-1094), Wydawca: The Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/d1ob02410h - link to the publication
  5. Monomeric and dimeric nitrate lanthanide(III) and yttrium(III) coordination compounds of (2+2) imine macrocycle derived from 2,6-diformylpyridine and trans-1,2-diaminocyclopentane
    Authors:
    Janusz Gregoliński, Katarzyna Ślepokura
    Academic press:
    polyhedron (rok: 2020, tom: 181, strony: 14433/1-114433/13), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.poly.2020.114433 - link to the publication

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