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New examples of enzyme catalytic promiscuity. Enzyme-catalyzed transformations of imines: stereoselective nitroalkane addition (aza-Henry reaction) and oxidation to oxaziridines using peroxidases

2016/23/B/ST5/02443

Keywords:

Enzyme catalytic promiscuity aza-Henry reaction peroxidases

Descriptors:

  • ST5_23:
  • ST5_25:

Panel:

ST5 - Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution :

Centrum Badań Molekularnych i Makromolekularnych Polskiej Akademii Nauk

woj. łódzkie

Other projects carried out by the institution 

Principal investigator (from the host institution):

prof. Piotr Kiełbasiński 

Number of co-investigators in the project: 3

Call: OPUS 12 - announced on 2016-09-15

Amount awarded: 744 500 PLN

Project start date (Y-m-d): 2017-07-18

Project end date (Y-m-d): 2024-01-17

Project duration:: 78 months (the same as in the proposal)

Project status: Project settled

Project description

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Note - project descriptions were prepared by the authors of the applications themselves and placed in the system in an unchanged form.

Information in the final report

  • Publication in academic press/journals (3)
  1. The first enzyme-promoted addition of nitromethane to imines (aza-Henry reaction)
    Authors:
    Ignacy Janicki, Piotr Łyżwa, Piotr Kiełbasiński
    Academic press:
    Bioorganic Chemistry (rok: 2020, tom: 94, strony: 103377), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.bioorg.2019.103377 - link to the publication
  2. "Quarter of a century after: a glimpse at the conformation and mechanism of Lipase B from Candida antarctica"
    Authors:
    Jarosław Błaszczyk, Piotr Kiełbasiński
    Academic press:
    Crystals (rok: 2020, tom: 10, strony: 404), Wydawca: MDPI
    Status:
    Published
    DOI:
    10.3390/cryst10050404 - link to the publication
  3. Towards Chemoenzymatic Syntheses of Both Enantiomers of Phosphoemeriamine
    Authors:
    Piotr Kiełbasiński,* Małgorzata Kwiatkowska, Piotr Łyżwa and Marian Mikołajczyk
    Academic press:
    Molecules (rok: 2024, tom: 29, strony: 1799), Wydawca: MDPI
    Status:
    Published
    DOI:
    10.3390/molecules2908179 - link to the publication

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