Projects funded by the NCN

Information on the principal investigator and host institution

Information of the project and the call

Keywords

Equipment

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Kinetics and mechanism of polymerization with organocatalysts with simultaneous function of initiators (INICAT). Properties of emerging polymers.

2016/23/B/ST5/02448

Keywords:

polymerization organic catalysts initiation of polymerization biodegrdable polymers.

Descriptors:

  • ST5_21:

Panel:

ST5 - Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution :

Centrum Badań Molekularnych i Makromolekularnych Polskiej Akademii Nauk

woj. łódzkie

Other projects carried out by the institution 

Principal investigator (from the host institution):

prof. Stanisław Penczek 

Number of co-investigators in the project: 4

Call: OPUS 12 - announced on 2016-09-15

Amount awarded: 1 102 450 PLN

Project start date (Y-m-d): 2017-09-04

Project end date (Y-m-d): 2022-09-03

Project duration:: 60 months (the same as in the proposal)

Project status: Project settled

Project description

Download the project description in a pdf file

Note - project descriptions were prepared by the authors of the applications themselves and placed in the system in an unchanged form.

Equipment purchased [PL]

  1. Laptop Lenovo (4 413 PLN)
  2. System wielokątowego rozpraszania światła (457 000 PLN)
  3. Notebook Acer.

Information in the final report

  • Publication in academic press/journals (9)
  • Book publications / chapters in book publications (1)
  1. Cationic Polymerization of Cyclic Trimethylene Carbonate Induced with Initiator and Catalyst in one Molecule: Polymer Structure, Kinetics and DFT.
    Authors:
    Krzysztof Kaluzynski, Julia Pretula, Sławomir Kaźmierski, Piotr Lewinski, Marek Cypryk, Stanislaw Penczek
    Academic press:
    Journal of Catalysis (rok: 2022, tom: 415, strony: 200-217), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.009 - link to the publication
  2. Catalysis in polymerization of cyclic esters. Catalyst and initiator in one molecule. Polymerization of e-caprolactone
    Authors:
    Krzysztof Kaluzynski, Julia Pretula, Piotr Lewinski, Sławomir Kaz´mierski, Stanislaw Penczek ⇑
    Academic press:
    Journal of Catalysis (rok: 2020, tom: 392, strony: 97-107), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.jcat.2020.09.026 - link to the publication
  3. "Dormant polymers and their role in living and controlled polymerizations; Influence on polymer chemistry, particularly on the ring opening polymerization"
    Authors:
    Stanislaw Penczek, Julia Pretula, Piotr Lewinski
    Academic press:
    Polymers (rok: 2017, tom: 9, strony: 646), Wydawca: MDPI
    Status:
    Published
    DOI:
    10.3390/polym9120646 - link to the publication
  4. Activated Monomer Mechanism (AMM) in Cationic Ring-Opening Polymerization. The Origin of the AMM and Further Development in Polymerization of Cyclic Esters
    Authors:
    Stanislaw Penczek* and Julia Pretula
    Academic press:
    ACS Macro Lett. (rok: 2021, tom: 10, strony: 1377-1397), Wydawca: ACS Publications
    Status:
    Published
    DOI:
    10.1021/ac - link to the publication
  5. Catalysis in polymerization of cyclic esters. Catalyst and initiator in one molecule. Polymerization of lactide
    Authors:
    Piotr Lewinski , Krzysztof Kaluzynski, Julia Pretula, Grazyna Mielniczak, Stanislaw Penczek
    Academic press:
    Journal of Catalysis (rok: 2022, tom: 405, strony: 249-264), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.jc - link to the publication
  6. Synthesis and Properties of Functionalized Poly(ε-caprolactone); Chain Polymerization Followed by Polycondensation in One Pot with Initiator and Catalyst in One Molecule. Synthesis and Molecular Structures
    Authors:
    Krzysztof Kaluzynski, Julia Pretula, Piotr Lewinski, Sławomir Kaźmierski, and Stanislaw Penczek
    Academic press:
    Macromolecules (rok: 2022, tom: 55(6), strony: 2210-2221), Wydawca: ACS
    Status:
    Published
    DOI:
    10.1021/ac - link to the publication
  7. Ring-opening polymerization
    Authors:
    Stanislaw Penczek*, Julia Pretula and Stanislaw Slomkowski
    Academic press:
    Chemistry Teacher International (rok: 2021, tom: 3(2), strony: 33-57), Wydawca: DE GRUYTER
    Status:
    Published
    DOI:
    10.1515/cti- - link to the publication
  8. ε-Caprolactone Polymerization Catalyzed by Heteropolyacid. Derivation of the Kinetic Equation for Activated Monomer Propagation and Determination of the Rate Constants of Propagation
    Authors:
    Krzysztof Kaluzynski, Piotr Lewinski, Julia Pretula, Ryszard Szymanski, Stanislaw Penczek
    Academic press:
    Macromolecules (rok: 2019, tom: 52, strony: 6405-6415), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.macromol.9b00672 - link to the publication
  9. ε-Caprolactone: Activated Monomer Polymerization; Controversy over the Mechanism of Polymerization Catalyzed by Phosphorus Acids (Diarylhydrogen Phosphates). Do Acids also Act as Initiators?
    Authors:
    Piotr Lewinski, Julia Pretula, Krzysztof Kaluzynski, Sławomir Kaźmierski, Stanislaw Penczek*
    Academic press:
    Journal of Catalysis (rok: 2019, tom: 371, strony: 305-312), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.jcat.2019.02.015 - link to the publication
  1. Ionic and Coordination Ring-Opening Polymerization
    Authors:
    Stanislaw Penczek, Tadeusz Biela, Marek Cypryk, Andrzej Duda, Grzegorz Lapienis, Przemyslaw Kubisa, Julia Pretula, Stanislaw Slomkowski, Ryszard Szymanski
    Book:
    Macromolecular Engineering: From Precise Synthesis to Macroscopic Materials and Applications, Second Edition. K. Matyjaszewski, Y. Gnanou, N. Hadjichristidis, M. Muthukumar. Eds. (rok: 2022, tom: 1, strony: 115-238), Wydawca: WILEY-VCH Weinahein
    Status:
    Published

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