Projects funded by the NCN

Information on the principal investigator and host institution

Information of the project and the call

Keywords

Equipment

Delete all

New catalysts for hydrometallation of alkenes and alkynes

2016/23/B/ST5/00177

Keywords:

catalysts hydrosilylation hydroboration Schiff bases trasition metal complexes. design and modification of ligands metal borohydrides

Descriptors:

  • ST5_18:
  • ST5_23:
  • ST5_14: Other related subjects

Panel:

ST5 - Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution :

Uniwersytet im. Adama Mickiewicza w Poznaniu, Wydział Chemii

woj. wielkopolskie

Other projects carried out by the institution 

Principal investigator (from the host institution):

dr hab. Piotr Pawluć 

Number of co-investigators in the project: 8

Call: OPUS 12 - announced on 2016-09-15

Amount awarded: 870 500 PLN

Project start date (Y-m-d): 2017-07-03

Project end date (Y-m-d): 2021-07-02

Project duration:: 48 months (the same as in the proposal)

Project status: Project settled

Project description

Download the project description in a pdf file

Note - project descriptions were prepared by the authors of the applications themselves and placed in the system in an unchanged form.

Equipment purchased [PL]

  1. Chemoodporna pompa olejowa o maksymalnej próżni 0,0001 torr (12 000 PLN)
  2. Zestaw komputerowy (4 000 PLN)
  3. System oczyszczania rozpuszczalników z podwójnym systemem sorbentów, rezerwuarami rozpuszczalników oraz pompą próżniową. (185 000 PLN)

Information in the final report

  • Publication in academic press/journals (10)
  1. Direct Dehydrogenative Coupling of Alcohols with Hydrosilanes Promoted by Sodium tri(sec-butyl)borohydride
    Authors:
    M. Skrodzki, M. Zaranek, S. Witomska, P. Pawluć
    Academic press:
    Catalysts (rok: 2018, tom: 8, strony: 618-624), Wydawca: MDPI Basel, Switzerland
    Status:
    Published
    DOI:
    0.3390/catal8120618 - link to the publication
  2. Searching for highly active cobalt catalysts bearing Schiff base ligands for Markovnikov-selective hydrosilylation of alkynes with tertiary silanes
    Authors:
    M. Skrodzki, V. Ortega Garrido, A.G. Csáky, P. Pawluc
    Academic press:
    Journal of Catalysis (rok: 2022, tom: 411, strony: 116-121), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.jcat.2022.05.002 - link to the publication
  3. Sodium triethylborohydride as a catalyst for the dehydrogenative silylation of terminal alkynes with hydrosilanes
    Authors:
    M. Skrodzki, S. Witomska, P. Pawluć
    Academic press:
    Dalton Transactions (rok: 2018, tom: 47, strony: 5948–5951), Wydawca: The Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/c8dt00684a - link to the publication
  4. Markovnikov Hydrosilylation of Alkenes: How an Oddity Becomes the Goal
    Authors:
    M. Zaranek. P. Pawluć
    Academic press:
    ACS Catalysis (rok: 2018, tom: 8, strony: 9865−9876), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acscatal.8b03104 - link to the publication
  5. The effect of Schiff base ligands on the structure and catalytic activity of cobalt complexes in hydrosilylation of olefins
    Authors:
    Aleksandra Bocian, Maciej Skrodzki, Maciej Kubicki, Adam Gorczyński, Piotr Pawluć, Violetta Patroniak
    Academic press:
    Applied Catalysis A General (rok: 2020, tom: 602, strony: 117665), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.apcata.2020.117665 - link to the publication
  6. Hydroboration of alkynes initiated by sodium triethylborohydride
    Authors:
    A.M. Maj, B. Szarłan, P. Pawluc,, M. Zaranek
    Academic press:
    Polyhedron (rok: 2022, tom: 223, strony: 115961-115965), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.poly.2022.115961 - link to the publication
  7. Schiff Base Cobalt(II) Complex-Catalyzed Highly Markovnikov-Selective Hydrosilylation of Alkyn
    Authors:
    Maciej Skrodzki, Violetta Patroniak, Piotr Pawluć
    Academic press:
    Organic Letters (rok: 2021, tom: 23, strony: 663-667), Wydawca: ACS
    Status:
    Published
    DOI:
    10.1021/acs.orglett.0c03721 - link to the publication
  8. Simple Schiff-Base Cu(II) Complexes as Efficient Catalysts for Benzyl Alcohol Oxidation
    Authors:
    W. Czepa, M.A. Fik, S. Witomska, M. Kubicki, G. Consiglio, P. Pawluć, V. Patroniak
    Academic press:
    Chemistry Select (rok: 2018, tom: 3, strony: 9504-9509), Wydawca: WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
    Status:
    Published
    DOI:
    10.1002/slct.2018015 - link to the publication
  9. DFT study of trialkylborohydride-catalysed hydrosilylation of alkenes – the mechanism and its implications
    Authors:
    M. Nowicki, M. Zaranek, P. Pawluć, M. Hoffmann
    Academic press:
    Catalysis Science & Technology (rok: 2020, tom: 10, strony: 1066-1072), Wydawca: The Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/C9CY02261A - link to the publication
  10. Markovnikov-selective double hydrosilylation of challenging terminal aryl alkynes under cobalt and iron catalysis
    Authors:
    Ł. Banach, D. Brykczyńska, A. Gorczyński, M. Skrodzki, P. Pawluć
    Academic press:
    Chemical Communications (rok: 2022, tom: -, strony: -), Wydawca: Royal Society of Chemistry
    Status:
    Submitted
    DOI:
    - - link to the publication

O Narodowym Centrum Nauki

Finansowanie nauki

Współpraca zagraniczna

Centrum prasowe

Deklaracja dostępności
Przetwarzanie danych osobowych
Polityka cookies

Partnerzy