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Biologically and catalytically relevant reactions of small molecules (NO, O2) activated on iron heme centers - models and mechanisms.

2016/23/D/ST4/00303

Keywords

Descriptors

  • ST4_14: Reakcje chemiczne: mechanizmy, termodynamika, kinetyka i kataliza
  • ST5_16: Chemia biologiczna
  • ST5_14: Chemia koordynacyjna

Panel

ST4 – Chemistry: physical chemistry/chemical physics, theoretical chemistry, analytical chemistry, inorganic chemistry, organic chemistry, method development

Host institution

Uniwersytet Jagielloński, Wydział Chemii

Voivodeship: małopolskie

Other projects carried out by the institution »

Principal investigator (from the host institution)

dr Maria Józefa Oszajca

Number of co-investigators in the project: 4

Call

SONATA 12 – announced on 2016-09-15

Amount awarded
526 100 PLN
Project start date
2017-07-18
Project end date
2021-07-17
Project duration
48 months (the same as in the proposal)
Project status
Project settled

Project description

Download the project description in a pdf file

Note — project descriptions were prepared by the authors of the applications themselves and placed in the system in an unchanged form.

Equipment purchased [PL]

  1. Elektroniczna waga analityczna. Cost: 10 000 PLN
  2. Komora rękawicowa z wyposażeniem typu GLOVEBOX do pracy w warunkach beztlenowych. Cost: 150 000 PLN
  3. Komputer do archiwizacji i przetwarzania danych wraz z oprogramowaniem. Cost: 5 000 PLN
  4. Reduktor do butli z gazami specjalnymi.
  5. Spektrofotometr. Cost: 40 000 PLN

Information in the final report

Publication in academic press/journals (5)

  1. Reaction of [RuIII(EDTA)(H2O/OH)]−/2− with bisulfide and persulfide in aqueous solution: kinetic andmechanistic studies

    Authors:
    M. Oszajca, D. Chatterjee, R. van Eldik
    Academic press:
    J. Coord. Chem. (year: 2019, volume: 72, pages: 2904-2915), Publisher: Taylor & Francis Group
    Status:
    Published
    DOI:
    10.1080/00958972.2019.1677899 – link to the publication

  2. High-Pressure Mechanistic Insight into Bioinorganic NO Chemistry

    Authors:
    Ł. Orzeł, M. Oszajca, J. Polaczek, D. Porębska, R. van Eldik, G. Stochel
    Academic press:
    Molecules (year: 2021, volume: 26 art. 4947, pages: 46046), Publisher: MDPI
    Status:
    Published

  3. Inorganic Reaction Mechanisms. A Personal Journey

    Authors:
    C. D. Hubbard, D. Chatterjee, M. Oszajca, J. Polaczek, O. Impert, M. Chrzanowska, A. Katafias, R. Puchta, R. van Eldik
    Academic press:
    Dalton Transactions (year: 2020, volume: 49, pages: 4599-4659), Publisher: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/c9dt04620h – link to the publication

  4. Phenolic Compounds of Reynoutria sp. as Modulators of Oral Cavity Lactoperoxidase System

    Authors:
    M. Magacz, M. Oszajca, I. Nawrot-Hadzik, R. Drodżdż, A. Jurczak, J. Hadzik, A. Smakosz, W. Krzyściak
    Academic press:
    ANTIOXIDANTS (year: 2021, volume: 10, art. nr 676, pages: 46043), Publisher: MDPI
    Status:
    Published
    DOI:
    10.3390/antiox10050676 – link to the publication

  5. Experimental and Computational Insight into the Mechanism of NO Binding to Ferric Microperoxidase. The Likely Role of Tautomerization to Account for the pH Dependence

    Authors:
    M. Oszajca, G. Drabik, M. Radoń, A. Franke, R. van Eldik, G. Stochel
    Status:
    Accepted for publication

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Graphic design and implementation: Jakub Piotrowski