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Information on the principal investigator and host institution

Information of the project and the call

Keywords

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Tandem palladium-catalyzed additions of enolates to alkynes followed by coupling with (hetero)aryl halides.

2016/22/E/ST5/00537

Keywords:

palladium

Descriptors:

  • ST5_23:
  • ST5_18:

Panel:

ST5 - Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution :

Instytut Chemii Organicznej Polskiej Akademii Nauk

woj. mazowieckie

Other projects carried out by the institution 

Principal investigator (from the host institution):

dr Wojciech Chaładaj 

Number of co-investigators in the project: 11

Call: SONATA BIS 6 - announced on 2016-06-15

Amount awarded: 1 994 900 PLN

Project start date (Y-m-d): 2017-04-11

Project end date (Y-m-d): 2023-04-10

Project duration:: 72 months (the same as in the proposal)

Project status: Project settled

Project description

Download the project description in a pdf file

Note - project descriptions were prepared by the authors of the applications themselves and placed in the system in an unchanged form.

Equipment purchased [PL]

  1. Aparat do mikrodestylacji (typu Kugelrohr).
  2. Zestaw komputerowy z oprogramowaniem specjalistycznym (9 000 PLN)
  3. Chromatograf gazowy (200 000 PLN)
  4. Zestaw do odparowywania (40 000 PLN)

Information in the final report

  • Publication in academic press/journals (6)
  1. Pd-catalyzed intramolecular addition of active methylene compounds to alkynes with subsequent cross-coupling with (hetero)aryl halides
    Authors:
    Aleksandra Błocka, Paweł Woźnicki, Marek Stankevič, Wojciech Chaładaj
    Academic press:
    RSC Advances (rok: 2019, tom: 9, strony: 40152), Wydawca: RSC
    Status:
    Published
    DOI:
    10.1039/c9ra08002c - link to the publication
  2. Tandem Pd-catalyzed annulation/coupling of acetylenic enamines with aryl triflates
    Authors:
    Aleksandra Błocka, Jakub Ostapko and Wojciech Chaładaj*
    Academic press:
    Chemical Communications (rok: 2023, tom: 59, strony: 5547-5550), Wydawca: RSC
    Status:
    Published
    DOI:
    10.1039/D3CC00671A - link to the publication
  3. Controllable Access to Furans and Dihydrofurans through Cyclization/Coupling of Internal Acetylenic β-Ketoesters with Aryl Bromides
    Authors:
    Bartosz Bisek, Wojciech Chaładaj*
    Academic press:
    Advanced Synthesis & Catalysis (rok: 2022, tom: 364, strony: 4281-4288), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/adsc.202200686 - link to the publication
  4. Efficient and Functional‐Group‐Tolerant Synthesis of Substituted Furans through the Pd‐Catalyzed 5‐exo‐dig Cyclization/Coupling of γ‐Acetylenic β‐Keto Esters with (Hetero)Aryl Bromides
    Authors:
    Agata Kołodziejczyk, Wojciech Chaładaj*
    Academic press:
    European Journal of Organic Chemistry (rok: 2018, tom: -, strony: 2554-2560), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/ejoc.201800046 - link to the publication
  5. Tandem Palladium-Catalyzed 6-exo-dig Oxocyclization-Coupling of δ-Acetylenic-β-ketoesters with Aryl Bromides and Chlorides: Efficient Route to Substituted Dihydropyrans
    Authors:
    Agata Kołodziejczyk, Sylwester Domański, Wojciech Chaładaj*
    Academic press:
    The Journal of Organic Chemistry (rok: 2018, tom: 83, strony: 12887–12896), Wydawca: American Chemical Society (ACS)
    Status:
    Published
    DOI:
    10.1021/acs.joc.8b01832 - link to the publication
  6. Tandem Pd-Catalyzed Cyclization/Coupling of Non-Terminal Acetylenic Activated Methylenes with (Hetero)Aryl Bromides †
    Authors:
    Aleksandra Błocka, Wojciech Chaładaj
    Academic press:
    Molecules (rok: 2022, tom: 27, strony: 630), Wydawca: MDPI
    Status:
    Published
    DOI:
    10.3390/molecules27030630 - link to the publication

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