Projects funded by the NCN

Information on the principal investigator and host institution

Information of the project and the call

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Organocatalytic synthetic strategies with the use of N-heterocyclic carbenes - new directions and applications

2016/22/E/ST5/00469

Keywords:

N-heterocyclic carbenes organocatalysis synergistic catalysis domino processes annulation reactions

Descriptors:

  • ST5_18:
  • ST5_23:

Panel:

ST5 - Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution :

Uniwersytet Mikołaja Kopernika w Toruniu, Wydział Chemii

woj. kujawsko-pomorskie

Other projects carried out by the institution 

Principal investigator (from the host institution):

dr Zbigniew Rafiński 

Number of co-investigators in the project: 7

Call: SONATA BIS 6 - announced on 2016-06-15

Amount awarded: 2 104 637 PLN

Project start date (Y-m-d): 2017-04-06

Project end date (Y-m-d): 2023-04-05

Project duration:: 72 months (the same as in the proposal)

Project status: Project settled

Project description

Download the project description in a pdf file

Note - project descriptions were prepared by the authors of the applications themselves and placed in the system in an unchanged form.

Information in the final report

  • Publication in academic press/journals (13)
  1. Construction of Highly Functionalized 2-Styrylfurans by N-Heterocyclic Carbene/Brønsted Acid Catalysis
    Authors:
    Izabela Barańska, Borys Ośmiałowski, Katarzyna Rafińska, Zbigniew Rafiński
    Academic press:
    Organic Letters (rok: 2024, tom: 26, strony: 3514-3518), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.orglett.4c00836 - link to the publication
  2. Synthesis of (−)-Verbenone-Derived Triazolium Salts and Their Application in Enantioselective Intramolecular Stetter Reaction
    Authors:
    Zbigniew Rafiński, Marek P. Krzemiński
    Academic press:
    Catalysts (rok: 2019, tom: 9, strony: 117), Wydawca: MDPI
    Status:
    Published
    DOI:
    10.3390/catal9020117 - link to the publication
  3. NHC-catalyzed enantioselective C2-functionalization of 3-hydroxychromenones via α,β-unsaturated acyl azoliums
    Authors:
    Krzesztof Dzieszkowski, Michał Słotwiński, Katarzyna Rafińska, Tadeusz M. Muzioł, Zbigniew Rafiński
    Academic press:
    Chemical Communications (rok: 2021, tom: 57, strony: 9999-10002), Wydawca: Royal Sociaty of Chemistry
    Status:
    Published
    DOI:
    10.1039/D1CC03708K - link to the publication
  4. Enantioselective synthesis of C3-functionalized 2,1-benzothiazine 2,2-dioxides by N-heterocyclic carbene catalysis
    Authors:
    Karina Mroczyńska, Liliana Dobrzańska, Zbigniew Rafiński
    Academic press:
    Chemical Communications (rok: 2024, tom: 60, strony: 7176-7179), Wydawca: Royal Sociaty of Chemistry
    Status:
    Published
    DOI:
    10.1039/d4cc01754d - link to the publication
  5. Enantioselective [3 + 3] Annulation–Deoxalation Strategy for Rapid Access to δ-Oxoesters via N-Heterocyclic Carbene Catalysis
    Authors:
    Izabela Barańska, Liliana Dobrzańska, Zbigniew Rafiński
    Academic press:
    Organic Letters (rok: 2024, tom: 26, strony: 1207-1211), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.orglett.3c04397 - link to the publication
  6. NHC-Catalyzed Organocatalytic Asymmetric Approach to 2,2-Disubstituted Benzofuran-3(2H)-ones Containing Fully Substituted Quaternary Stereogenic Center
    Authors:
    Zbigniew Rafiński
    Academic press:
    Catalysts (rok: 2019, tom: 9, strony: 192), Wydawca: MDPI
    Status:
    Published
    DOI:
    10.3390/catal9020192 - link to the publication
  7. Enantioselective Synthesis of Aza-Flavanones with an All-Carbon Quaternary Stereocenter via NHC-Catalyzed Intramolecular Annulation
    Authors:
    Izabela Barańska, Michał Słotwiński, Tadeusz Muzioł, Zbigniew Rafiński
    Academic press:
    ACS Omega (rok: 2023, tom: 8, strony: 41480-41484), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acsomega.3c05064 - link to the publication
  8. N‐Heterocyclic Carbene‐Catalyzed Enantioselective Intramolecular Annulations to Construct Benzo‐Fused Pyranones with Quaternary Stereocenter
    Authors:
    Krzysztof Dzieszkowski, Zbigniew Rafiński
    Academic press:
    Advanced Synthesis and Catalysis (rok: 2020, tom: 362, strony: 3830-3835), Wydawca: Wiley-VCh
    Status:
    Published
    DOI:
    10.1002/adsc.202000550 - link to the publication
  9. CONSTRUCTION OF DIHYDROPYRIDO[2,3-D]PYRIMIDINE SCAFFOLDS VIA AZA-CLAISEN REARRANGEMENT CATALYZED BY N-HETEROCYCLIC CARBENES
    Authors:
    Krzysztof Dzieszkowski, Izabela Barańska, Zbigniew Rafiński
    Academic press:
    The Journal of Organic Chemistry (rok: 2020, tom: 85, strony: 6645-6662), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.joc.0c00657 - link to the publication
  10. N-Heterocyclic Carbene Catalysis under Oxidizing Conditions
    Authors:
    Krzysztof Dzieszkowski, Zbigniew Rafiński
    Academic press:
    Catalysts (rok: 2018, tom: 8, strony: 549), Wydawca: MDPI
    Status:
    Published
    DOI:
    10.3390/catal8110549 - link to the publication
  11. N-Heterocyclic Carbene Organocatalyzed [3+3] Annulation for the Enantioselective Synthesis of Benzopyranothiazinones
    Authors:
    Karina Mroczyńska, Zbigniew Rafiński
    Academic press:
    Advanced Synthesis & Catalysis (rok: 2024, tom: 366, strony: 1285-1290), Wydawca: Wiley-VCH GmbH
    Status:
    Published
    DOI:
    10.1002/adsc.202301082 - link to the publication
  12. Enantioselective Synthesis of Highly Substituted Fluoroalkylated Benzopyranones and 3-Coumaranones via NHC-Catalyzed Intramolecular Annulations
    Authors:
    Izabela Barańska, Katarzyna Rafińska, Zbigniew Rafiński
    Academic press:
    The Journal of Organic Chemistry (rok: 2023, tom: 88, strony: 14339-14344), Wydawca: American Chemical Society
    Status:
    Accepted for publication
    DOI:
    10.1021/acs.joc.3c01099 - link to the publication
  13. Organocatalytic Name Reactions Enabled by NHCs
    Authors:
    Krzysztof Dzieszkowski, Izabela Barańska, Karina Mroczyńska, Michał Słotwiński, Zbigniew Rafiński
    Academic press:
    Materials (rok: 2020, tom: 13, strony: 3574), Wydawca: MDPI
    Status:
    Published
    DOI:
    10.3390/ma13163574 - link to the publication

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