A new look at the phenomenon of up-conversion in nanoparticles doped with lanthanide ions: synthesis of core/shell structures and studies of emission under radiation from the second and third biological window

2016/22/E/ST5/00016

Keywords

Descriptors

  • ST5_10: Nanomateriały: nanocząstki, nanorurki
  • ST5_12: Materiały "inteligentne" – materiały samoorganizujące się, materiały reagujące na bodźce zewnętrzne
  • ST5_24: Chemia nieorganiczna

Panel

ST5 – Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution

Uniwersytet im. Adama Mickiewicza w Poznaniu, Wydział Chemii

Voivodeship: wielkopolskie

Other projects carried out by the institution »

Principal investigator (from the host institution)

dr Tomasz Grzyb

Number of co-investigators in the project: 6

Call

SONATA BIS 6 – announced on 2016-06-15

Amount awarded
1 929 300 PLN
Project start date
2017-03-30
Project end date
2022-09-29
Project duration
66 months (the same as in the proposal)
Project status
Project settled

Project description

Download the project description in a pdf file

Note — project descriptions were prepared by the authors of the applications themselves and placed in the system in an unchanged form.

Equipment purchased [PL]

  1. Analizator wielkości nanocząstek i potencjału dzeta - Zetasizer Nano ZS. Cost: 330 000 PLN
  2. Komputer (2 pcs). Cost: 6 000 PLN
  3. Laptop. Cost: 4 000 PLN
  4. Laser półprzewodnikowy. Cost: 30 000 PLN
  5. Moduł do rejestracji widm emisji i zaników luminescencji w zakresie 950 – 1600 nm.
  6. Reaktor do syntez nanocząstek. Cost: 30 000 PLN
  7. Rozbudowa układu do pomiarów wydajności kwantowej emisji.. Cost: 20 000 PLN
  8. Suszarka.
  9. Waga analityczna.
  10. Wyparka.
  11. stacja dokująca.

Information in the final report

Publication in academic press/journals (17)

  1. Upconverting SrF2:Er3+ Nanoparticles for Optical Temperature Sensors

    Authors:
    Sylwia Ryszczyńska, Karolina Trejgis, Łukasz Marciniak, Tomasz Grzyb
    Academic press:
    ACS Applied Nano Materials (year: 2021, volume: 4, pages: 10438−10448), Publisher: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acsanm.1c01964 – link to the publication
  2. Manipulation of up-conversion emission in NaYF4 core@shell nanoparticles doped by Er3+, Tm3+, or Yb3+ ions by excitation wavelength—three ions—plenty of possibilities

    Authors:
    Tomasz Grzyb, Piotr Kamiński, Dominika Przybylska, Artur Tymiński, F. Sanz-Rodríguezb, Patricia Haro Gonzalez
    Academic press:
    Nanoscale (year: 2021, volume: 13, pages: 7322-7333), Publisher: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/D0NR07136F – link to the publication
  3. Upconversion in Detail: Multicolor Emission of Yb/Er/Tm‐Doped Nanoparticles under 800, 975, 1208, and 1532 nm Excitation Wavelengths

    Authors:
    Artur Tymiński, Inocencio R. Martín, Tomasz Grzyb
    Academic press:
    Particle & Particle Systems Characterization (year: 2020, volume: 37, pages: 2000068), Publisher: Wiley
    Status:
    Published
    DOI:
    10.1002/ppsc.202000068 – link to the publication
  4. Formation Mechanism, Structural, and Upconversion Properties of Alkaline Rare-Earth Fluoride Nanocrystals Doped With Yb3+/Er3+ Ions

    Authors:
    Tomasz Grzyb, Dominika Przybylska
    Academic press:
    Inorganic Chemistry (year: 2018, volume: 57, pages: 6410−6420), Publisher: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.inorgchem.8b00484 – link to the publication
  5. Synthesis and up-conversion of core/shell SrF2:Yb3+,Er3+@SrF2:Yb3+,Nd3+ nanoparticles under 808, 975, and 1532 nm excitation wavelengths

    Authors:
    Dominika Przybylska , Tomasz Grzyb
    Academic press:
    Journal of Alloys and Compounds (year: 2020, volume: 831, pages: 154797), Publisher: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.jallcom.2020.154797 – link to the publication
  6. Upconverting SrF2 nanoparticles doped with Yb3+/Ho3+, Yb3+/Er3+ and Yb3+/Tm3+ ions – optimisation of synthesis method, structural, spectroscopic and cytotoxicity studies

    Authors:
    Dominika przybylska, Anna Ekner-Grzyb, Bartosz F. Grześkowiak, Tomasz Grzyb
    Academic press:
    Scientific Reports (year: 2019, volume: 9, pages: 8669), Publisher: Nature Publishing Group
    Status:
    Published
    DOI:
    10.1038/s41598-019-45025-1 – link to the publication
  7. Ultraviolet- and Near-Infrared-Excitable LaPO 4 :Yb 3+ /Tm 3+ /Ln 3+ (Ln = Eu, Tb) Nanoparticles for Luminescent Fibers and Optical Thermometers

    Authors:
    Artur Tymiński, Emilia Śmiechowicz, Inocencio R. Martín, and Tomasz Grzyb
    Academic press:
    ACS Applied Nano Materials (year: 2020, volume: 3, pages: 6541-6551), Publisher: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acsanm.0c01025 – link to the publication
  8. Tailoring structure, morphology and up-conversion properties of CaF2:Yb3+,Er3+ nanoparticles by the route of synthesis

    Authors:
    Dominika Przybylska, Tomasz Grzyb
    Academic press:
    Journal of Materials Science (year: 2020, volume: 55, pages: 14166-14178), Publisher: Springer
    Status:
    Published
    DOI:
    10.1007/s10853-020-05049-9 – link to the publication
  9. Sr 2 LuF 7 :Yb 3+ –Ho 3+ –Er 3+ Upconverting Nanoparticles as Luminescent Thermometers in the First, Second, and Third Biological Windows

    Authors:
    Marcin Runowski, Szymon Goderski, Dominika Przybylska, Tomasz Grzyb, Stefan Lis, Inocencio R. Martín
    Academic press:
    ACS Applied Nano Material (year: 2020, volume: 3, pages: 6406–6415), Publisher: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acsanm.0c00839 – link to the publication
  10. Improvement of ligand‑free modification strategy to obtain water‑stable up‑converting nanoparticles with bright emission and high reaction yield

    Authors:
    Natalia Jurga, Dominika Przybylska, Piotr Kamiński, Tomasz Grzyb
    Academic press:
    Scientific Reports (year: 2021, volume: 11, pages: 18846), Publisher: Nature Research
    Status:
    Published
    DOI:
    10.1038/s41598-021-98240-0 – link to the publication
  11. Improvement in Luminescence Intensity of β-NaYF4: 18%Yb3+, 2%Er3+@β-NaYF4 Nanoparticles as a Result of Synthesis in the Presence of Stearic Acid

    Authors:
    Piotr Kaminski, Dominika Przybylska, Gabriela Klima, Tomasz Grzyb
    Academic press:
    Nanomaterials (year: 2022, volume: 12, pages: 319), Publisher: MDPI
    Status:
    Published
    DOI:
    10.3390/nano12030319 – link to the publication
  12. Bi3+ as an enhancer for down- and upconversion luminescence in ternary vanadate structures

    Authors:
    NinaKaczorowska, AgataSzczeszak, StefanLis
    Academic press:
    Ceramics International (year: 2021, volume: 47, pages: 24182-24190), Publisher: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.ceramint.2021.05.129 – link to the publication
  13. NIR-to-NIR and NIR-to-Vis up-conversion of SrF2:Ho3+ nanoparticles under 1156 nm excitation

    Authors:
    Sylwia Ryszczyska, Tomasz Grzyb
    Academic press:
    Methods and Applications in Fluorescence (year: 2022, volume: 10, pages: 24001), Publisher: IOP Publishing
    Status:
    Published
    DOI:
    10.1088/2050-6120/ac4999 – link to the publication
  14. Functionalization of cellulose fibers and paper with lanthanide-based luminescent core/shell nanoparticles providing 3-level protection for advanced anti-counterfeiting purposes

    Authors:
    A. Szczeszak, M. Skwierczyńska, D. Przybylska, M. Runowski, E. Śmiechowicz, A. Erdman, O. Ivashchenko, T. Grzyb, P. Kulpiński, K. Olejnik
    Academic press:
    Materials and Design (year: 2022, volume: 218, pages: 110684), Publisher: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.matdes.2022.110684 – link to the publication
  15. Influence of the synthesis route on the spectroscopic, cytotoxic, and temperature-sensing properties of oleate-capped and ligand-free core/ shell nanoparticles

    Authors:
    Natalia Jurga, Dominika Przybylska, Piotr Kaminski, Artur Tyminnski, Bartosz F. Grzeskowiak, Tomasz Grzyb
    Academic press:
    Journal of Colloid and Interface Science (year: 2022, volume: 606, pages: 1421-1434), Publisher: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.jcis.2021.08.093 – link to the publication
  16. Anti-Counterfeiting System Based on Luminescent Varnish Enriched by NIR- Excited Nanoparticles for Paper Security

    Authors:
    D. Przybylska, T. Grzyb, A. Erdman, K. Olejnik, A. Szczeszak
    Academic press:
    Scientific Reports (year: 2022, volume: 12, pages: 19388), Publisher: Nature
    Status:
    Published
    DOI:
    10.1038/s41598-022-23686-9 – link to the publication
  17. Multifunctional Cellulose Fibers: Intense Red Upconversion under 1532 Nm Excitation and Temperature-Sensing Properties

    Authors:
    T. Grzyb, D. Przybylska, A. Szczeszak, E. Śmiechowicz, P. Kulpiński, I.R. Martín
    Academic press:
    Carbohydrate Polymers (year: 2022, volume: 294, pages: 119782), Publisher: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.carbpol.2022.119782 – link to the publication

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Graphic design and implementation: Jakub Piotrowski