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Frustrated Lewis Pairs (FLP): new class of phosphorus compounds with applications in synthetic chemistry and catalysis.

2016/21/B/ST5/03088

Keywords:

phosphorus frustrated Lewis pairs catalysis

Descriptors:

  • ST5_24:
  • ST5_8: Metals, alloys
  • ST5_18:

Panel:

ST5 - Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution :

Politechnika Gdańska, Wydział Chemiczny

woj. pomorskie

Other projects carried out by the institution 

Principal investigator (from the host institution):

dr hab. Rafał Grubba 

Number of co-investigators in the project: 6

Call: OPUS 11 - announced on 2016-03-15

Amount awarded: 466 500 PLN

Project start date (Y-m-d): 2017-07-19

Project end date (Y-m-d): 2020-07-18

Project duration:: 36 months (the same as in the proposal)

Project status: Project settled

Project description

Download the project description in a pdf file

Note - project descriptions were prepared by the authors of the applications themselves and placed in the system in an unchanged form.

Equipment purchased [PL]

  1. Pompa próżniowa (10 000 PLN)
  2. Reaktor ciśnieniowy (15 000 PLN)
  3. Stacja robocza do obliczeń DFT (20 000 PLN)
  4. Oprogramowanie do obliczeń DFT - Amsterdam Density Functional (ADF) (25 000 PLN)

Information in the final report

  • Publication in academic press/journals (10)
  1. Diaminophosphinoboranes: effective reagents for phosphinoboration of CO2.
    Authors:
    Natalia Szynkiewicz, Anna Ordyszewska, Jarosław Chojnacki, Rafał Grubba
    Academic press:
    RSC Advances (rok: 2019, tom: 9, strony: 27749–27753), Wydawca: The Royal Society of Chemistry (RSC)
    Status:
    Published
    DOI:
    10.1039/c9ra06638a - link to the publication
  2. Syntheses, Structures and Reactivity of Terminal Phosphido Complexes of Iron(II) Supported by a β-Diketiminato Ligand
    Authors:
    Kinga Kaniewska, Alina Dragulescu-Andrasi, Łukasz Ponikiewski, Jerzy Pikies,Sebastian A. Stoian, Rafał Grubba
    Academic press:
    European Journal of Inorganic Chemistry (rok: 2018, tom: 2018, strony: 4298–4308), Wydawca: Wiley-VCH
    Status:
    Published
    DOI:
    10.1002/ejic.201800850 - link to the publication
  3. Activation of N2O and SO2 by the P-B bond system. Reversible binding of SO2 by the P-O-B geminal frustrated Lewis pair.
    Authors:
    Natalia Szynkiewicz, Jarosław Chojnacki, Rafał Grubba
    Academic press:
    Inorganic Chemistry (rok: 2020, tom: 59, strony: 6332–6337), Wydawca: The American Chemical Society (ACS)
    Status:
    Published
    DOI:
    10.1021/acs.inorgchem.0c00435 - link to the publication
  4. Structural and spectroscopic analysis of a new family of monomeric diphosphinoboranes
    Authors:
    Anna Ordyszewska, Natalia Szynkiewicz, Emil Perzanowski, Jarosław Chojnacki, Aleksandra Wiśniewska, Rafał Grubba
    Academic press:
    Dalton Transactions (rok: 2019, tom: 48, strony: 12482–12495), Wydawca: The Royal Society of Chemistry (RSC)
    Status:
    Published
    DOI:
    10.1039/c9dt02195g - link to the publication
  5. Bonding in Phosphanylphosphinidene Complexes of Transition Metals and their Correlation with Structures, 31P NMR Spectra, and Reactivities
    Authors:
    Mateusz Zauliczny, Anna Ordyszewska, Jerzy Pikies, Rafał Grubba
    Academic press:
    European Journal of Inorganic Chemistry (rok: 2018, tom: 2018, strony: 3131–3141), Wydawca: Wiley-VCH
    Status:
    Published
    DOI:
    10.1002/ejic.201800270 - link to the publication
  6. Diphosphination of CO2 and CS2 mediated by frustrated Lewis pairs – catalytic route to phosphanyl derivatives of formic and dithioformic acid
    Authors:
    Natalia Szynkiewicz, Łukasz Ponikiewski, Rafał Grubba
    Academic press:
    Chemical Communications (rok: 2019, tom: 55, strony: 2928--2931), Wydawca: The Royal Society of Chemistry (RSC)
    Status:
    Published
    DOI:
    10.1039/c9cc00621d - link to the publication
  7. Diphosphinoboranes as Intramolecular Frustrated Lewis Pairs: P−B−P Bond Systems for the Activation of Dihydrogen, Carbon Dioxide, and Phenyl Isocyanate
    Authors:
    Natalia Szynkiewicz, Anna Ordyszewska, Jarosław Chojnacki, Rafał Grubba
    Academic press:
    Inorganic Chemistry (rok: 2021, tom: 60, strony: 3794−3806), Wydawca: The American Chemical Society (ACS)
    Status:
    Published
    DOI:
    10.1021/acs.inorgchem.0c03563 - link to the publication
  8. Reactivity of bulky aminophosphanes towards small molecules: activation of dihydrogen and carbon dioxide by aminophosphane/borane frustrated Lewis pairs
    Authors:
    Magdalena Siedzielnik, Kinga Kaniewska-Laskowska, Natalia Szynkiewicz, Jarosław Chojnacki, Rafał Grubba
    Academic press:
    Polyhedron (rok: 2021, tom: 194, strony: 114930-114942), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.poly.2020.114930 - link to the publication
  9. Symmetrical and unsymmetrical diphosphanes with diversified alkyl, aryl, and amino substituents
    Authors:
    Natalia Szynkiewicz, Łukasz Ponikiewski, Rafał Grubba
    Academic press:
    Dalton Transactions (rok: 2018, tom: 47, strony: 16885–16894), Wydawca: The Royal Society of Chemistry (RSC)
    Status:
    Published
    DOI:
    10.1039/c8dt03775b - link to the publication
  10. The new diphosphanylphosphido complexes of tungsten(VI) and molybdenum(VI). Their synthesis, structures and properties
    Authors:
    Aleksandra Wiśniewska, Rafał Grubba, Łukasz Ponikiewski, Mateusz Zauliczny, Jerzy Pikies
    Academic press:
    Dalton Transactions (rok: 2018, tom: 47, strony: 10213–10222), Wydawca: The Royal Society of Chemistry (RSC)
    Status:
    Published
    DOI:
    10.1039/c8dt01977k - link to the publication

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