Projects funded by the NCN

Information on the principal investigator and host institution

Information of the project and the call

Keywords

Equipment

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Palladium-catalyzed perfluoroalkylative functionalyzation of alkynes

2016/21/B/ST5/03178

Keywords:

Fluoroorganic compounds Alkines Palladium Multicomponent reactions Tandem reactions

Descriptors:

  • ST5_23:
  • ST5_18:
  • ST5_14: Other related subjects

Panel:

ST5 - Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution :

Instytut Chemii Organicznej Polskiej Akademii Nauk

woj. mazowieckie

Other projects carried out by the institution 

Principal investigator (from the host institution):

dr Wojciech Chaładaj 

Number of co-investigators in the project: 7

Call: OPUS 11 - announced on 2016-03-15

Amount awarded: 1 195 900 PLN

Project start date (Y-m-d): 2017-01-18

Project end date (Y-m-d): 2020-12-17

Project duration:: 47 months (the same as in the proposal)

Project status: Project settled

Project description

Download the project description in a pdf file

Note - project descriptions were prepared by the authors of the applications themselves and placed in the system in an unchanged form.

Equipment purchased [PL]

  1. Pompy membranowa z kontrolerem próżni.
  2. Zesatw do badań pod ciśnieniem (typu nacynia Fishera-Portera) (30 000 PLN)
  3. Zestaw do odparowywania (40 000 PLN)
  4. Komputer z oprogramowaniem specjalistycznym (9 000 PLN)
  5. Stacja oczyszczania rozpuszczalników (160 000 PLN)
  6. Zestaw Próżniowy Schlenka (30 000 PLN)

Information in the final report

  • Publication in academic press/journals (4)
  1. Palladium‐Catalyzed Carboperfluoroalkylation of Alkynes with Fluoroalkyl Iodides and Arylstannanes
    Authors:
    Nitinkumar Satyadev Upadhyay, Wojciech Chaładaj
    Academic press:
    Advanced Synthesis & Catalysis (rok: 2020, tom: 362, strony: 493-499), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/adsc.201901027 - link to the publication
  2. Pd-Catalyzed Perfluoroalkylative Aryloxycarbonylation of Alkynes with Formates as CO Surrogates
    Authors:
    Beata Gatlik, Wojciech Chaładaj
    Academic press:
    ACS Catalysis (rok: 2021, tom: 11, strony: 6547–6559), Wydawca: ACS
    Status:
    Published
    DOI:
    10.1021/acscatal.1c00671 - link to the publication
  3. Pd-Catalyzed Carbonylative Carboperfluoroalkylation of Alkynes. Through-Space 13C–19F Coupling as a Probe for Configuration Assignment of Fluoroalkyl-Substituted Olefins
    Authors:
    Sylwester Domański, Olga Staszewska-Krajewska, Wojciech Chaładaj
    Academic press:
    The Journal of Organic Chemistry (rok: 2017, tom: 82, strony: 7998–8007), Wydawca: ACS
    Status:
    Published
    DOI:
    10.1021/acs.joc.7b01236 - link to the publication
  4. Pd-Catalyzed Boroperfluoroalkylation of Alkynes Opens a Route to One-Pot Reductive Carboperfluoroalkylation of Alkynes with Perfluoroalkyl and Aryl Iodides
    Authors:
    Sylwester Domański, Beata Gatlik, Wojciech Chaładaj
    Academic press:
    Organic Letters (rok: 2019, tom: 21, strony: 5021−5025), Wydawca: ACS
    Status:
    Published
    DOI:
    10.1021/acs.orglett.9b01618 - link to the publication

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