Projects funded by the NCN

Information on the principal investigator and host institution

Information of the project and the call

Keywords

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Synthesis and reactivity of 1-halopolyynes.

2015/19/B/ST5/02917

Keywords:

halopolyynes coupling radical enynes Sonogashira

Descriptors:

  • ST5_9: Biomaterials, biocompatible materials
  • ST5_20:
  • ST5_23:

Panel:

ST5 - Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution :

Uniwersytet Wrocławski, Wydział Chemii

woj. dolnośląskie

Other projects carried out by the institution 

Principal investigator (from the host institution):

dr hab. Sławomir Szafert 

Number of co-investigators in the project: 6

Call: OPUS 10 - announced on 2015-09-15

Amount awarded: 820 000 PLN

Project start date (Y-m-d): 2016-07-08

Project end date (Y-m-d): 2019-07-07

Project duration:: 36 months (the same as in the proposal)

Project status: Project settled

Project description

Download the project description in a pdf file

Note - project descriptions were prepared by the authors of the applications themselves and placed in the system in an unchanged form.

Equipment purchased [PL]

  1. Komputer stacjonarny DELL (10 976 PLN)
  2. Mieszadła magnetyczne (10 494 PLN)
  3. Kompaktowa łuskarka do lodu.
  4. Chłodziarka cyrkulacyjna.
  5. Pompy próżniowa (2 szt.) (40 000 PLN)
  6. Wyparka próżniowa.
  7. Wysokosprawna chromatografia cieczowa (280 000 PLN)
  8. Zasilacz do lampy TQ150.

Information in the final report

  • Publication in academic press/journals (7)
  1. Selective synthesis of iridium(III) end-capped polyynes by oxidative addition of 1-iodopolyynes to Vaska's complex
    Authors:
    Bartłomiej Pigulski, Agata Jarszak, Sławomir Szafert
    Academic press:
    Dalton Transactions (rok: 2018, tom: 47, strony: 17046-17054), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/c8dt04219e - link to the publication
  2. Polyynes as Precursors of Photoluminescent Solvent Polarity Probes
    Authors:
    Bartłomiej Pigulski, Jakub Cichos, and Sławomir Szafert
    Academic press:
    ACS Sustainable Chemistry & Engineering (rok: 2017, tom: 5, strony: 7077-7085), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acssuschemeng.7b01274 - link to the publication
  3. Reactivity of 3-halopropynols: X-ray crystallographic analysis of 1,1- dihalocumulenes and 2+2 cycloaddition products
    Authors:
    Nurbey Gulia, Bartłomiej Pigulski, and Sławomir Szafert
    Academic press:
    Arkivoc (rok: 2017, tom: iii, strony: 191-204), Wydawca: Arkat USA, Inc.
    Status:
    Published
    DOI:
    10.133 - link to the publication
  4. Crystal Engineering of 1-Halopolyynes by End-Group Manipulation
    Authors:
    Bartłomiej Pigulski, Nurbey Gulia, Patrycja Męcik, Robert Wieczorek, Agata Arendt, Sławomir Szafert
    Academic press:
    Crystal Growth and Design (rok: 2019, tom: 19, strony: 6542-6551), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.cgd.9b00987 - link to the publication
  5. Synthesis, characterization and thermal properties of T8 type amido-POSS with p-halophenyl end-group
    Authors:
    Mateusz Janeta, Sławomir Szafert
    Academic press:
    Journal of Organometallic Chemistry (rok: 2017, tom: 847, strony: 173-183), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.jorganchem.2017.05.044 - link to the publication
  6. Use of Stable Amine-Capped Polyynes in the Regioselective Synthesis of Push−Pull Thiophenes
    Authors:
    Bartłomiej Pigulski, Patrycja Męcik, Jakub Cichos, and Sławomir Szafert
    Academic press:
    The Journal of Organic Chemistry (rok: 2017, tom: 82, strony: 1487-1498), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.joc.6b02685 - link to the publication
  7. Reactivity of Polyynes: Complex Molecules from Simple Carbon Rods
    Authors:
    Bartłomiej Pigulski, Nurbey Gulia, Sławomir Szafert
    Academic press:
    European Journal of Organic Chemistry (rok: 2019, tom: 7, strony: 1420-1445), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/ejoc.201801350 - link to the publication

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