Projects funded by the NCN

Information on the principal investigator and host institution

Information of the project and the call

Keywords

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An application of new catalytic reactions of chiral 4-vinyl- and 4-ethynyl-azetidin-2-ones in the stereodivergent synthesis of nonracemic heterocyclic compounds.

2015/19/D/ST5/00713

Keywords:

beta-lactams stereodivergent synthesis homoallylic alcohols homoallylic amines allenes heterocyclic compounds

Descriptors:

  • ST5_18:
  • ST5_23:

Panel:

ST5 - Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution :

Instytut Chemii Organicznej Polskiej Akademii Nauk

woj. mazowieckie

Other projects carried out by the institution 

Principal investigator (from the host institution):

dr Bartosz Zambroń 

Number of co-investigators in the project: 4

Call: SONATA 10 - announced on 2015-09-15

Amount awarded: 412 000 PLN

Project start date (Y-m-d): 2016-07-20

Project end date (Y-m-d): 2020-07-19

Project duration:: 48 months (the same as in the proposal)

Project status: Project settled

Project description

Download the project description in a pdf file

Note - project descriptions were prepared by the authors of the applications themselves and placed in the system in an unchanged form.

Equipment purchased [PL]

  1. Wyparka próżniowa wraz z pompą i kontrolerem próżni. (35 000 PLN)
  2. Komputer wraz z monitorem i oprogramowaniem (4 000 PLN)
  3. Mieszadło magnetyczne z grzaniem i termostatem. (2 szt.) (8 000 PLN)
  4. Pompa próżniowa olejowa (15 000 PLN)

Information in the final report

  • Publication in academic press/journals (4)
  1. Acyclic remote 1,5- and 1,4,5-stereocontrol in the catalytic stereoselective reactions of β-lactams with aldehydes. The effect of N-methylimidazole ligand.
    Authors:
    Paulina Plata, Urszula Klimczak, Bartosz Zambroń
    Academic press:
    The Journal of Organic Chemistry (rok: 2018, tom: 83, strony: 14527-14552), Wydawca: ACS Publications
    Status:
    Published
    DOI:
    10.1021/acs.joc.8b02333 - link to the publication
  2. Internal Chelation within Functionalized Organoindium Reagents: Prospects for Regio- and Stereocontrol in the Allylation, Propargylation and Allenylation of Carbonyl Compounds.
    Authors:
    Zambroń Bartosz
    Academic press:
    Synthesis (rok: 2020, tom: 52, strony: 1147-1180), Wydawca: Thieme Chemistry
    Status:
    Published
    DOI:
    10.1055/s-0039-1690817 - link to the publication
  3. Diastereoselectivity switch in the Pd(0)/InI-mediated reactions of β- lactams with aldehydes. An entry into nonracemic semi-protected (3E)-2,6-enediols.
    Authors:
    Domin, Sylwia; Plata, Paulina; Zambroń, Bartosz
    Academic press:
    The Journal of Organic Chemistry (rok: 2019, tom: 84, strony: 12268-12280), Wydawca: ACS Publications
    Status:
    Published
    DOI:
    10.1021/acs.joc.9b01471 - link to the publication
  4. Remote 1,5-Stereoselectivity Control by an N-Ligand Switch in the Pd(0)/Inl-Promoted Reactions of 4-Ethynyl-β-lactams with Aldehydes.
    Authors:
    Domin, Sylwia; Kędzierski, Jacek; Zambroń, Bartosz
    Academic press:
    Organic Letters (rok: 2019, tom: 21, strony: 3904-3908), Wydawca: ACS Publications
    Status:
    Published
    DOI:
    10.1021/acs.orglett.9b00891 - link to the publication

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