Projects funded by the NCN

Information on the principal investigator and host institution

Information of the project and the call

Keywords

Equipment

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Impact of High pressure and spatial confinement on the kinetics of polymerization and isomerization.Towards better control over the progress of reaction.

2015/18/E/ST4/00320

Keywords:

High pressure nanopores polymerization tautomerization

Descriptors:

  • ST4_2: Spectroscopic and spectrometric techniques
  • ST4_14: Catalysis
  • ST5_6: Porous materials, ceramics, glasses

Panel:

ST4 - Chemistry: physical chemistry/chemical physics, theoretical chemistry, analytical chemistry, inorganic chemistry, organic chemistry, method development

Host institution :

Uniwersytet Śląski w Katowicach, Wydział Nauk Ścisłych i Technicznych

woj. śląskie

Other projects carried out by the institution 

Principal investigator (from the host institution):

dr hab. Kamil Kamiński 

Number of co-investigators in the project: 6

Call: SONATA BIS 5 - announced on 2015-06-15

Amount awarded: 1 953 360 PLN

Project start date (Y-m-d): 2016-04-01

Project end date (Y-m-d): 2022-03-31

Project duration:: 72 months (the same as in the proposal)

Project status: Project settled

Project description

Download the project description in a pdf file

Note - project descriptions were prepared by the authors of the applications themselves and placed in the system in an unchanged form.

Equipment purchased [PL]

  1. Linia laserowa do Ramana 785 nm (130 000 PLN)
  2. doposażenie spektrometru UV-VIS-NIR (JASCO V-770) (130 000 PLN)
  3. Chromarograf SEC/GPC-ELSD (250 000 PLN)
  4. Stanowisko do produkcji materiałów nanoporowatych o ściśle zdefiniowanej geometrii oraz wąskiej dystrybucji rozmiarów porów (11 439 PLN)

Information in the final report

  • Publication in academic press/journals (24)
  1. Efficient metal-free strategies of polymerization of sterically hindered ionic monomer through the application of hard confinement and high pressure.
    Authors:
    P. Maksym, M. Tarnacka, A. Dzienia, K. Wolnica, M. Dulski, K. Erfurt, A. Chrobok, A. Zięba, A. Brzózka, G. Sulka, R. Bielas, K. Kaminski, M. Paluch
    Academic press:
    RSC Advances (rok: 2019, tom: 9, strony: 6396-6408), Wydawca: The Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/c8ra09242g - link to the publication
  2. High-Pressure Studies on the Chain and Segmental Dynamics of a Series of Poly(propylene glycol) Derivatives
    Authors:
    A. Talik, M. Tarnacka, A. Dzienia, E. Kaminska, K. Kaminski, M. Paluch
    Academic press:
    Macromolecules (rok: 2019, tom: 52, strony: 5658-5669), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.macromol.9b00692 - link to the publication
  3. Highly Efficient ROP Polymerization of ε-caprolactone Catalyzed by Nanoporous Alumina Membranes. How the Confinement Affects the Progress and Product of ROP Reaction.
    Authors:
    Magdalena Tarnacka, Andrzej Dzienia, Paulina Maksym, Agnieszka Talik, Andrzej Zięba, Rafał Bielas, Kamil Kamiński*, Marian Paluch
    Academic press:
    Macromolecules (rok: 2018, tom: 51, strony: 4588-4597), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.macromol.8b00409 - link to the publication
  4. Studying tautomerism in an important pharmaceutical Glibenclamide confined in the thin nanometric layers.
    Authors:
    K. Wolnica, G. Szklarz, M. Dulski, M. Wojtyniak, M. Tarnacka, E. Kaminska, R. Wrzalik, K. Kaminski, M. Paluch,
    Academic press:
    Colloids and Surfaces B: Biointerfaces (rok: 2019, tom: 182, strony: 110319), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.colsurfb.2019.06.049 - link to the publication
  5. A facile route to well-defined imidazolium-based poly(ionic liquid)s of enhanced conductivity via RAFT.
    Authors:
    Paulina Maksym, Magdalena Tarnacka, Andrzej Dzienia, Karol Erfurt, Anna Chrobok, Andrzej Zięba, Kamila Wolnica, Kamil Kaminski, Marian Paluch
    Academic press:
    Polymer Chemistry (rok: 2017, tom: 8, strony: 5433-5443), Wydawca: The Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/C7PY01046J - link to the publication
  6. The impact of liquid crystalline phase ordering on the thermodynamic scaling of itraconazole.
    Authors:
    D. Heczko, E. Kamińska, M. Tarnacka, K. Koperwas, A. Dzienia, M. Chorzążewski, K. Kamiński, M. Paluch,
    Academic press:
    The Journal of Chemical Physics C (rok: 2019, tom: 123, strony: 4558-45566), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.jpcc.8b12074 - link to the publication
  7. A study on the progress of mutarotation above and below the Tg and the relationship between constant rates and structural relaxation times
    Authors:
    Kamila Wolnica, Mateusz Dulski, Ewa Kaminska, Adam Cecotka, Magdalena Tarnacka, Roman Wrzalik, Kamil Kaminski, Marian Paluch
    Academic press:
    Physical Chemistry Chemical Physics (rok: 2017, tom: 19, strony: 20949-20958), Wydawca: The Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/C7CP02046E - link to the publication
  8. How does the type of counterion influence the polymerization rate and thermal properties of tailored choline-based linear and star-shaped poly(ionic liquid)s PILs?
    Authors:
    Paulina Maksym, Magdalena Tarnacka, Kamila Wolnica, Andrzej Dzienia, Andrzej Zięba, Kamil Kamiński, Marian Paluch
    Academic press:
    Journal of Polymer Science, Part A: Polymer Chemistry (rok: 2018, tom: 56, strony: 2681-2691), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/pola.29252 - link to the publication
  9. Studies on dynamics and isomerism in supercooled photochromic compound- Aberchrome 670 with the use of different experimental techniques.
    Authors:
    Wioletta Edyta Śmiszek-Lindert, Ewa Kamińska, Aldona Minecka, Dawid Heczko, Olga Madejczyk, Magdalena Tarnacka, Karolina Jurkiewicz, Andrzej Dzienia, Kamil Kamiński, Maluch Paluch
    Academic press:
    Physical Chemistry Chemical Physics (rok: 2018, tom: 20, strony: 18009-18019), Wydawca: The Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/c8cp02993h - link to the publication
  10. Studies on the radical polymerization of monomeric ionic liquids: nanostructure ordering as a key factor controlling the reaction and properties of nascent polymers
    Authors:
    Magdalena Tarnacka, Anna Chrobok, Karolina Matuszek, Dorota Neugebauer, Rafał Bielas, Sylwia Golba, Kamila Wolnica, Mateusz Dulski, Kamil Kaminski,Marian Paluch
    Academic press:
    Polymer Chemistry (rok: 2016, tom: 7, strony: 6363-6374), Wydawca: The Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/c6py01274d - link to the publication
  11. Correlation between Locally Ordered (Hydrogen-Bonded) Nanodomains and Puzzling Dynamics of Polymethysiloxane Derivative
    Authors:
    Magdalena Tarnacka*, Karolina Jurkiewicz, Barbara Hachuła, Zaneta Wojnarowska, Roman Wrzalik, Rafał Bielas, Agnieszka Talik, Paulina Maksym, Kamil Kaminski*, and Marian Paluch
    Academic press:
    Macromolecules (rok: 2020, tom: 53, strony: 10225−10233), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.macromol.0c01289 - link to the publication
  12. Enhanced Polymerization Rate and Conductivity of Ionic Liquids-based Epoxy Resin.
    Authors:
    Paulina Maksym, Magdalena Tarnacka, Andrzej Dzienia, Karolina Matuszek, Anna Chrobok, Kamil Kaminski, Marian Paluch,
    Academic press:
    Macromolecules (rok: 2017, tom: 50, strony: 5188-5193), Wydawca: American Chemical Science
    Status:
    Published
    DOI:
    10.1021/acs.macromol.6b02749 - link to the publication
  13. Experimental (FTIR, BDS) and theoretical analysis of mutarotation kinetics of D-fructose mixed with different alcohols in the supercooled region
    Authors:
    Mateusz Dulski, Adam Cecotka, Satya Tripathy, Artur Sakalouski, Kamila Wolnica, Magdalena Tarnacka, Roman Wrzalik, Kamil Kaminski, Marian Paluch
    Academic press:
    RSC Advances (rok: 2016, tom: 6, strony: 57634-57646), Wydawca: The Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/c6ra13266a - link to the publication
  14. High pressure as a novel tool for the cationic ROP of gamma-butyrolactone.
    Authors:
    R. Bernat, P. Maksym, M. Tarnacka, K. Malarz, A. Mrozek-Wilczkiewicz, T. Biela, S. Golba, E. Kamińska, M. Paluch, K. Kamiński
    Academic press:
    RSC Advances (rok: 2021, tom: 11, strony: 34806-34819), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/D1RA06081C - link to the publication
  15. Polymerization of Monomeric Ionic Liquid Confined within Uniaxial Alumina Pores as a New Way of Obtaining Materials with Enhanced Conductivity
    Authors:
    Magdalena Tarnacka,Anna Chrobok, Karolina Matuszek, Sylwia Golba, Paulina Maksym, Kamil Kaminski,Marian Paluch
    Academic press:
    ACS Interfaces and Applied Materials (rok: 2016, tom: 8, strony: 29779−29790), Wydawca: American Chemical Science
    Status:
    Published
    DOI:
    10.1021/acsami.6b10666 - link to the publication
  16. Studies on the hard confinement effect on the RAFT polymerization of a monomeric ionic liquid. Unexpected triggering of RAFT polymerization at 30 degrees C.
    Authors:
    Paulina Maksym, Magdalena Tarnacka, Kamila Wolnica, Andrzej Dzienia, Karol Erfurt, Anna Chrobok, Andrzej Zięba, Rafał Bielas, Kamil Kamiński, Marian Paluch
    Academic press:
    Polymer Chemistry (rok: 2018, tom: 9, strony: 335-345), Wydawca: The Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/C7PY01726J - link to the publication
  17. Studying catalytic activity of DBU and TBD upon water-initiated ROP of ε-caprolactone at different thermodynamic conditions.
    Authors:
    A. Dzienia, P. Maksym, B. Hachuła, M. Tarnacka, T. Biela, S. Golba, M. Chorążewski, A. Zięba, K. Kaminski, M. Paluch
    Academic press:
    Polymer Chemistry (rok: 2019, tom: 10, strony: 6048-6061), Wydawca: The Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/C9PY01134J - link to the publication
  18. The effect of high pressure on organocatalyzed ROP of gamma-butyrolactone.
    Authors:
    R. Bernat, P. Maksym, M. Tarnacka, K. Koperwas, J. Knapik-Kowalczuk, K. Malarz, A. Mrozek-Wilczkiewicz, A. Dzienia, T. Biela, R. Turczyn, L. Orszulak, B. Hachuła, M. Paluch, K. Kamiński
    Academic press:
    Polymer (rok: 2021, tom: 233, strony: 124166), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1039/D1RA06081C - link to the publication
  19. Unexpected Crossover in the kinetics of mutarotation in the supercooled region: the role of H-bonds.
    Authors:
    Kamila Wolnica, Mateusz Dulski, Ewa Kamińska, Magdalena Tarnacka, Roman Wrzalik, Wioletta Edyta Śmiszek-Lindert, Kamil Kamiński, Marian Paluch
    Academic press:
    Scientific Reports (rok: 2018, tom: 8, strony: 5312-5322), Wydawca: Nature
    Status:
    Published
    DOI:
    10.1038/s41598-018-23117-8 - link to the publication
  20. Direct insight into the kinetics of the high-pressure step-growth polymerization of DGEBA/aniline model system.
    Authors:
    A. Dzienia, K. Koperwas, M. Tarnacka, M. Chorążewski, E. B. Postnikov, A. R. Lowe, K. Kamiński and M. Paluch
    Academic press:
    Polymer (rok: 2019, tom: 172, strony: 322-329), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.polymer.2019.04.001 - link to the publication
  21. High pressure RAFT of sterically hindered ionic monomers. Studying relationship between rigidity of the polymer backbone and conductivity
    Authors:
    Paulina Maksym, Andrzej Dzienia, Magdalena Tarnacka, Karol Erfurt, Alina Brzęczek-Szafran, Anna Chrobok, Andrzej Zięba, Kamil Kamiński, Marian Paluch
    Academic press:
    Polymer (rok: 2018, tom: 140, strony: 158-166), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.polymer.2018.02.030 - link to the publication
  22. High pressure water-initiated Ring Opening Polymerization in the synthesis of well-defined alpha-hydroxy-omega-(carboxylic acid) polycaprolactones.
    Authors:
    Andrzej Dzienia, Paulina Maksym, Magdalena Tarnacka, Iwona Grudzka-Flak, Sylwia. Golba, Andrzej Zięba, Kamil Kaminski, Marian Paluch,
    Academic press:
    Green Chemistry (rok: 2017, tom: 19, strony: 3618-3627), Wydawca: The Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/C7GC01748K - link to the publication
  23. Impact of Imidazolium-Based Ionic Liquids on the Curing Kinetics and Physicochemical Properties of Nascent Epoxy Resins
    Authors:
    Andrzej Dzienia*, Magdalena Tarnacka, Kajetan Koperwas, Paulina Maksym, Andrzej Ziȩba, Joanna Feder-Kubis, Kamil Kamiński*, and Marian Paluch
    Academic press:
    Macromolecules (rok: 2020, tom: 53, strony: 6341-6352), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.macromol.0c00783 - link to the publication
  24. The application of spatially restricted geometries as a unique route to produce well-defined poly(vinyl pyrrolidones) via free radical polymerization.
    Authors:
    M. Tarnacka, P. Maksym, A. Zięba, A. Mielańczyk, M. Geppert-Rybczyńska, L. Leon-Boigues, C. Mijangos, K. Kamiński, M. Paluch
    Academic press:
    Chemical Communication (rok: 2019, tom: 55, strony: 6441-6444), Wydawca: The Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/c9cc02625h - link to the publication

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