A new approach to the anion-pi interactions: supramolecular adducts based on anionic d-electron metal ion complexes and pi-electron deficient organic molecules.
2014/15/B/ST5/02098
Keywords
Descriptors
- ST5_22: Chemia supramolekularna
- ST4_4: Struktura i architektura molekularna
- ST4_15: Chemia teoretyczna i obliczeniowa
Panel
ST5 – Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering
Host institution
Uniwersytet Jagielloński, Wydział Chemii
Voivodeship: małopolskie
Principal investigator (from the host institution)
Number of co-investigators in the project: 7
Call
OPUS 8 – announced on 2014-09-15
- Amount awarded
- 679 980 PLN
- Project start date
- 2015-07-08
- Project end date
- 2020-01-07
- Project duration
- 54 months (the same as in the proposal)
- Project status
- Project settled
Equipment purchased [PL]
- Dewar ciśnieniowy.
- Monitor przeznaczony do pracy komputerem.
- Oprogramowanie EndNote (5 pcs). Cost: 5 000 PLN
- Przystawka niskotemperaturowa z dewarem na ciekły azot, przystosowana do pracy z dyfraktometrem rentgenowskim.
- Termostat chłodząco-grzejący o objętość roboczej 4,5 L i zakresie temperatur od -28 do + 100oC. Cost: 14 000 PLN
- Zestaw mieszadeł magnetycznych z funkcją grzania T = RT - 340oC i maksymalną liczbą obrotów 1200 obr/min. (4 pcs). Cost: 22 000 PLN
- kompleksowy zestaw wagowy dedykowany do syntezy i charakterystyki nowych materiałów supramolekularnych (4 pcs). Cost: 22 000 PLN
- Źródła promieniowania rentgenowskiego dedykowane do dyfraktometrów rentgenowskich (2 pcs). Cost: 65 000 PLN
Information in the final report
Publication in academic press/journals (5)
-
Molecular deformation, charge flow, and sponge-like behavior in anion-π {[M(CN)4]2-;[HAT(CN)6]} (M = Ni, Pd, Pt) supramolecular stacks
- Authors:
- Emilia Kuzniak, Dawid Pinkowicz, James Hooper, Monika Srebro-Hooper, Łukasz Hetmańczyk, Robert Podgajny
- Academic press:
- Chemistry - A European Journal (year: 2018, volume: 24, pages: 16302–16314), Publisher: Wiley
- Status:
- Published
- DOI:
- 10.1002/chem.201802933 – link to the publication
-
Anion-π architectures of HAT(CN)6 and 5d polycyanidometalates: [W(CN)8]3-, [Re(CN)7]3-, and [Pt(CN)6]2-
- Authors:
- Jędrzej Kobylarczyk, Dawid Pinkowicz, Monika Srebro-Hooper, James Hooper, Robert Podgajny
- Academic press:
- Crystal Growth & Design (year: 2019, volume: 19, pages: 1215-1225), Publisher: The American Chemical Society
- Status:
- Published
- DOI:
- 10.1021/acs.cgd.8b01653 – link to the publication
-
Rotating Magnetocaloric Effect in an Anisotropic Two-Dimensional CuII[WV(CN)8]3− Molecular Magnet with Topological Phase Transition: Experiment and Theory
- Authors:
- Piotr Konieczny,* Robert Pełka, Dominik Czernia, and Robert Podgajny*
- Academic press:
- Inorganic Chemistry (year: 2017, volume: 56, pages: 11971-11980), Publisher: American Chemical Society
- Status:
- Published
- DOI:
- 10.1021/acs.inorgchem.7b01930 – link to the publication
-
A concerted evolution of supramolecular interactions in a {cation; metal complex; π-acid; solvent} anion-π system
- Authors:
- Emilia Kuzniak, James Hooper, Monika Srebro-Hooper, Jedrzej Kobylarczyk, Magdalena Dziurka, Bogdan Musielak, Dawid Pinkowicz, Jesus Raya, Sylvie Ferlay and Robert Podgajny*
- Academic press:
- Inorganic Chemistry Frontiers (year: 2020, volume: 7, pages: 1851–1863), Publisher: The Royal Society of Chemistry
- Status:
- Published
- DOI:
- 10.1039/d0qi00101e – link to the publication
-
Anion–π recognition between [M(CN)6]3− complexes and HAT(CN)6: structural matching and electronic charge density modification
- Authors:
- Jedrzej Kobylarczyk, Dawid Pinkowicz, Monika Srebro-Hooper, James Hooper and Robert Podgajny*
- Academic press:
- Dalton Transactions (year: 2017, volume: 46, pages: 3482-3491), Publisher: The Royal Society of Chemistry
- Status:
- Published
- DOI:
- 10.1039/c7dt00293a – link to the publication