Projects funded by the NCN


Information on the principal investigator and host institution

Information of the project and the call

Keywords

Equipment

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A new approach to the anion-pi interactions: supramolecular adducts based on anionic d-electron metal ion complexes and pi-electron deficient organic molecules.

2014/15/B/ST5/02098

Keywords:

anion complexes organic pi-acids supramolecular adducts electronic structure anion-pi interactions

Descriptors:

  • ST5_22:
  • ST4_4: Theoretical and computational chemistry
  • ST4_15: Colloid chemistry

Panel:

ST5 - Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution :

Uniwersytet Jagielloński, Wydział Chemii

woj. małopolskie

Other projects carried out by the institution 

Principal investigator (from the host institution):

dr hab. Robert Podgajny 

Number of co-investigators in the project: 7

Call: OPUS 8 - announced on 2014-09-15

Amount awarded: 679 980 PLN

Project start date (Y-m-d): 2015-07-08

Project end date (Y-m-d): 2020-01-07

Project duration:: 54 months (the same as in the proposal)

Project status: Project settled

Equipment purchased [PL]

  1. Dewar ciśnieniowy.
  2. Monitor przeznaczony do pracy komputerem.
  3. Przystawka niskotemperaturowa z dewarem na ciekły azot, przystosowana do pracy z dyfraktometrem rentgenowskim.
  4. Zestaw mieszadeł magnetycznych z funkcją grzania T = RT - 340oC i maksymalną liczbą obrotów 1200 obr/min. (4 szt.) (22 000 PLN)
  5. Źródła promieniowania rentgenowskiego dedykowane do dyfraktometrów rentgenowskich (2 szt.) (65 000 PLN)
  6. Oprogramowanie EndNote (5 szt.) (5 000 PLN)
  7. Termostat chłodząco-grzejący o objętość roboczej 4,5 L i zakresie temperatur od -28 do + 100oC (14 000 PLN)
  8. kompleksowy zestaw wagowy dedykowany do syntezy i charakterystyki nowych materiałów supramolekularnych (4 szt.) (22 000 PLN)

Information in the final report

  • Publication in academic press/journals (5)
  1. Anion-π architectures of HAT(CN)6 and 5d polycyanidometalates: [W(CN)8]3-, [Re(CN)7]3-, and [Pt(CN)6]2-
    Authors:
    Jędrzej Kobylarczyk, Dawid Pinkowicz, Monika Srebro-Hooper, James Hooper, Robert Podgajny
    Academic press:
    Crystal Growth & Design (rok: 2019, tom: 19, strony: 1215-1225), Wydawca: The American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.cgd.8b01653 - link to the publication
  2. A concerted evolution of supramolecular interactions in a {cation; metal complex; π-acid; solvent} anion-π system
    Authors:
    Emilia Kuzniak, James Hooper, Monika Srebro-Hooper, Jedrzej Kobylarczyk, Magdalena Dziurka, Bogdan Musielak, Dawid Pinkowicz, Jesus Raya, Sylvie Ferlay and Robert Podgajny*
    Academic press:
    Inorganic Chemistry Frontiers (rok: 2020, tom: 7, strony: 1851–1863), Wydawca: The Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/d0qi00101e - link to the publication
  3. Anion–π recognition between [M(CN)6]3− complexes and HAT(CN)6: structural matching and electronic charge density modification
    Authors:
    Jedrzej Kobylarczyk, Dawid Pinkowicz, Monika Srebro-Hooper, James Hooper and Robert Podgajny*
    Academic press:
    Dalton Transactions (rok: 2017, tom: 46, strony: 3482-3491), Wydawca: The Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/c7dt00293a - link to the publication
  4. Molecular deformation, charge flow, and sponge-like behavior in anion-π {[M(CN)4]2-;[HAT(CN)6]} (M = Ni, Pd, Pt) supramolecular stacks
    Authors:
    Emilia Kuzniak, Dawid Pinkowicz, James Hooper, Monika Srebro-Hooper, Łukasz Hetmańczyk, Robert Podgajny
    Academic press:
    Chemistry - A European Journal (rok: 2018, tom: 24, strony: 16302–16314), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/chem.201802933 - link to the publication
  5. Rotating Magnetocaloric Effect in an Anisotropic Two-Dimensional CuII[WV(CN)8]3− Molecular Magnet with Topological Phase Transition: Experiment and Theory
    Authors:
    Piotr Konieczny,* Robert Pełka, Dominik Czernia, and Robert Podgajny*
    Academic press:
    Inorganic Chemistry (rok: 2017, tom: 56, strony: 11971-11980), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.inorgchem.7b01930 - link to the publication