Unsymmetric difluoroboranes - synthesis, spectral and theoretical studies of new fluorescent probes

2013/09/B/ST5/03550

Keywords

Descriptors

  • ST5_23: Chemia organiczna
  • ST5_9: Materiały do konstrukcji sensorów
  • ST4_15: Chemia teoretyczna i obliczeniowa

Panel

ST5 – Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution

Uniwersytet Technologiczno-Przyrodniczy im. Jana i Jędrzeja Śniadeckich w Bydgoszczy, Wydział Technologii i Inżynierii Chemicznej

Voivodeship: kujawsko-pomorskie

Other projects carried out by the institution »

Principal investigator (from the host institution)

dr hab. Borys Bartosz Ośmiałowski

Number of co-investigators in the project: 7

Call

OPUS 5 – announced on 2013-03-15

Amount awarded
627 042 PLN
Project start date
2014-03-03
Project end date
2017-03-02
Project duration
36 months (the same as in the proposal)
Project status
Project settled

Equipment purchased [PL]

  1. spektrofluorymetr. Cost: 130 000 PLN

Information in the final report

Publication in academic press/journals (11)

  1. Synthesis and photophysical properties of novel donor-acceptor N-(pirydyn-2-yl) substituted benzo(thio)amides and their difluoroboranyl derivatives

    Authors:
    Beata Jędrzejewska, Šimon Budzák, Małgorzata A. Kaczorowska, Anna Zakrzewska, Karina Mroczyńska, Grzegorz Mlostoń, Anna Maria Grabarz, Denis Jacquemin, Borys Ośmiałowski
    Academic press:
    J. Phys. Chem. A (year: 2016, volume: 120, pages: 4116-4123), Publisher: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.jpca.6b04004 – link to the publication
  2. Tuning the Electronic Properties of the Dative N-B Bond with Associated O-B Interaction: Electron Localizability Indicator from X-Ray Wavefunction Refinement

    Authors:
    Lilianna Chęcińska, Stefan Mebs, Borys Ośmiałowski, Anna Zakrzewska, Krzysztof Ejsmont, M. Kohout
    Academic press:
    ChemPhysChem (year: 2016, volume: 17, pages: 2395-2406), Publisher: Wiley
    Status:
    Published
    DOI:
    10.1002/cphc.201600223 – link to the publication
  3. Two-photon absorption of BF2-carrying compounds: insights from theory and experiment

    Authors:
    Joanna Bednarska, Robert Zaleśny, Małgorzata Wielgus, Beata Jędrzejewska, Rakesh Puttreddy, Kari Rissanen, Wojciech Bartkowiak, Hans Agren, Borys Ośmiałowski
    Academic press:
    Phys.Chem.Chem.Phys. (year: 2017, volume: 19, pages: 5705-5708), Publisher: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/c7cp00063d – link to the publication
  4. The influence of the π-conjugated spacer on photophysical properties of difluoroboranyls derived from amides carrying donor group

    Authors:
    Anna Maria Grabarz, Adèle D. Laurent, Beata Jędrzejewska, Anna Zakrzewska, Denis Jacquemin, Borys Ośmiałowski
    Academic press:
    J. Org. Chem. (year: 2016, volume: 81, pages: 2280-2292), Publisher: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.joc.5b02691 – link to the publication
  5. Influence of Substituent and Benzoannulation on Photophysical Properties of 1‐Benzoylmethyleneisoquinoline Difluoroborates

    Authors:
    Borys Ośmiałowski, Anna Zakrzewska, Beata Jędrzejewska, Anna Grabarz, Robert Zaleśny, Wojciech Bartkowiak, Erkki Kolehmainen
    Academic press:
    Journal of Organic Chemistry (year: 2015, volume: 80, pages: 2072-2080), Publisher: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/jo502244j – link to the publication
  6. Toward Fully Nonempirical Simulations of Optical Band Shapes of Molecules in Solution: A Case Study of Heterocyclic Ketoimine Difluoroborates

    Authors:
    Robert Zaleśny, N. Arul Murugan, Faris Gel'mukhanov, Zilvinas Rinkevicius, Borys Ośmiałowski, Wojciech Bartkowiak, Hans Ågren
    Academic press:
    Journal of Physical Chemistry A (year: 2015, volume: 119, pages: 5145-5152), Publisher: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/jp5094417 – link to the publication
  7. First-Principles Simulations of One- and Two-Photon Absorption Band Shapes of the Bis(BF2) Core Complex

    Authors:
    Robert Zaleśny, Murugan Natarajan Arul, Guangjun Tian, Miroslav Medved, Hans Ågren
    Academic press:
    J. Phys. Chem. B (year: 2016, volume: 120, pages: 2323-2332), Publisher: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.jpcb.5b09726 – link to the publication
  8. Spectral and physicochemical properties of difluoroboranyls containing N,N-dimethylamino group studied by solvatochromic methods

    Authors:
    Beata Jędrzejewska, Anna Grabarz, Wojciech Bartkowiak, Borys Ośmiałowski
    Academic press:
    Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy (year: 2018, volume: 199, pages: 86-95), Publisher: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.saa.2018.03.048 – link to the publication
  9. Photophysical Properties of Phenacylphenantridine Difluoroboranyls: Effect of Substituent and Double Benzannulation

    Authors:
    Anna Maria Grabarz, Beata Jędrzejewska, Anna Zakrzewska, Robert Zaleśny, Adele D. Laurent, Denis Jacquemin, Borys Ośmiałowski
    Academic press:
    J. Org. Chem. (year: 2017, volume: 82, pages: 1529-1537), Publisher: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.joc.6b02732 – link to the publication
  10. Collision induced dissociation of N-(pyridin-2-yl)-substituted benzo(thio)amides and N-(isoquinolin-1-yl)furan(thiophene)-2-carboxamides and their difluoroboranyl derivatives

    Authors:
    Małgorzata A. Kaczorowska, Borys Ośmiałowski
    Academic press:
    International Journal of Mass Spectrometry (year: 2018, volume: 428, pages: 35-42), Publisher: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.ijms.2018.02.006 – link to the publication
  11. Difluoroboranyl Derivatives as Efficient Panchromatic Photoinitiators in Radical Polymerization Reactions

    Authors:
    Beata Jędrzejewska, Borys Ośmiałowski
    Status:
    Accepted for publication

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