Low pressure catalitic synthesis of novel beta-lactone monomers and their anionic ring-opening (co)polymerization leading to synthetic analogues of aliphatic biopolyesters

2012/07/B/ST5/00627

Keywords

Descriptors

  • ST5_11: Synteza biomateriałów
  • ST5_21: Chemia polimerów
  • ST5_23: Chemia organiczna

Panel

ST5 – Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution

Centrum Materiałów Polimerowych i Węglowych PAN

Voivodeship: śląskie

Other projects carried out by the institution »

Principal investigator (from the host institution)

prof. Marek Marian Kowalczuk

Number of co-investigators in the project: 8

Call

OPUS 4 – announced on 2012-09-15

Amount awarded
895 200 PLN
Project start date
2013-06-19
Project end date
2016-06-18
Project duration
36 months (the same as in the proposal)
Project status
Project settled

Equipment purchased [PL]

  1. Drukarka 3D dwugłowicowa.
  2. Oprogramowanie do drukarki 3D.
  3. Spektrofluorymetr Cary Eclipse - kompletny zestaw. Cost: 110 000 PLN
  4. Źródło jonów DESI firmy Prosolia model OS-3001 kompatybilne ze spektrometrem mas LCQ Fleet firmy Thermo Scientific , będącym na wyposażeniu Centrum Materiałów Polimerowych i Węglowych PAN w Zabrzu. Cost: 155 000 PLN

Information in the final report

Publication in academic press/journals (9)

  1. Bioactive (co)oligoesters with antioxidant properties – synthesis and structural characterization at the molecular level

    Authors:
    M. Maksymiak, T. Bałakier, J. Jurczak, M. Kowalczuk, G. Adamus
    Academic press:
    RSC Adv. (year: 2016, volume: 6, pages: 57751-57761), Publisher: The Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/c6ra09870c – link to the publication
  2. Synthesis and structural characterization at the molecular level of oligo(3-hydroxybutyrate) conjugates with antimicrobial agents designed for food packaging materials

    Authors:
    I. Kwiecień, G. Adamus, A. Bartkowiak, M. Kowalczuk
    Academic press:
    Des Monomers Polym (year: 2014, volume: 17(4), pages: 311-321), Publisher: Taylor & Francis Group
    Status:
    Published
    DOI:
    10.1080/15685551.2013.840505 – link to the publication
  3. New vistas in mass spectrometry for sequence analysis of natural and synthetic biodegradable macromolecules

    Authors:
    M. Kowalczuk
    Academic press:
    Chim Oggi - Chemistry Today (year: 2016, volume: 34(2), pages: 46371), Publisher: TeknoScienze Publisher
    Status:
    Published
  4. Molecular level structure of novel synthetic analogues of aliphatic biopolyesters as revealed by multistage mass spectrometry

    Authors:
    G. Adamus, I. Kwiecień, M. Maksymiak, T. Bałakier, J. Jurczak, M. Kowalczuk
    Academic press:
    Anal. Chim. Acta (year: 2014, volume: 808, pages: 104-114), Publisher: ScienceDirect
    Status:
    Published
    DOI:
    10.1016/j.aca.2013.09.001 – link to the publication
  5. Molecular architecture of novel potentially bioactive (co)oligoesters containing pesticide moieties established by electrospray ionization multistage mass spectrometry

    Authors:
    I. Kwiecień, T. Bałakier, J. Jurczak, M. Kowalczuk, G. Adamus
    Academic press:
    Rapid Comunn. Mass Spectrom. (year: 2015, volume: 29, pages: 533-544), Publisher: Wiley
    Status:
    Published
    DOI:
    link to the publication
  6. Forensic engineering of advanced polymeric materials. Part III - Biodegradation of thermoformed rigid PLA packaging under industrial composting conditions

    Authors:
    M. Musioł, W. Sikorska, G. Adamus, H. Janeczek, J. Richert, R. Malinowski, G. Jiang, M. Kowalczuk
    Academic press:
    Waste Manage. (year: 2016, volume: 52, pages: 69-76), Publisher: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.wasman.2016.04.016 – link to the publication
  7. (Bio)degradable polymers as a potential material for food packaging: studies on the (bio)degradation process of PLA/(R,S)-PHB rigid foils under industrial composting conditions

    Authors:
    M Musiol, W. Sikorska, G. Adamus, H. Janeczek, M. Kowalczuk, J. Rydz
    Academic press:
    Eur. Food Res. Technol. (year: 2016, volume: 242, pages: 815-823), Publisher: Springer
    Status:
    Published
    DOI:
    10.1007/s00217-015-2611-y – link to the publication
  8. Mass spectrometry for the elucidation of the subtle molecular structure of biodegradable polymers and their degradation products

    Authors:
    M. Kowalczuk, G. Adamus
    Academic press:
    Mass Spectrom. Rev. (year: 2016, volume: 35, pages: 188-198), Publisher: Wiley
    Status:
    Published
    DOI:
    10.1002/mas.21474 – link to the publication
  9. Forensic engineering of advanced polymeric materials. Part 1 – degradation studies of polylactide blends with atactic poly[(R,S)-3-hydroxybutyrate] in paraffin

    Authors:
    J. Rydz, K. Wolna-Stypka, G. Adamus, H. Janeczek, M. Musioł, M. Sobota, A. Marcinkowski, A. Krzan, M. Kowalczuk
    Academic press:
    Chem. Biochem. Eng. Q. (year: 2015, volume: 29(2), pages: 247-259), Publisher: Yugoslav Committee for Chemical Engineering; Society of Chemists and Chemical Engineers of Croatia
    Status:
    Published
    DOI:
    10.15255/CABEQ.2014.2258 – link to the publication

Articles in post-conference publications (6)

  1. FORENSIC ENGINEERING OF ADVANCED POLYMERIC BIOMATERIALS (Invited Lecture)

    Authors:
    Marek M. Kowalczuk
    Conference:
    2nd Annual ISBPPB's Conference & Exposition (year: 2015, pages: #), Publisher: International Society for Biomedical Polymers and Polymeric Biomaterials
    Date:
    conference July 8-9
    Status:
    Published
  2. Structural studies of bioactive (co)oligoesters with antioxidant properties by electrospray ionization tandem mass spectrometry (P42)

    Authors:
    Magdalena Maksymiak, Tomasz Bałakier, Janusz Jurczak, Marek Kowalczuk, Grażyna Adamus
    Conference:
    Silesian Meetings on Polymer Materials, POLYMAT 2016 (year: 2016, pages: 43), Publisher: Centrum Materiałów Polimerowych i Węglowych PAN
    Date:
    conference 46931
    Status:
    Published
  3. Resorbable fibrous polymers in terms of forensic engineering of advanced polymeric materials (Invited Lecture)

    Authors:
    Marek Kowalczuk
    Conference:
    5th International Conference Smart and Multifunctional Materials Structures & Systems (year: 2016, pages: L-3:IL03), Publisher: CIMTEC
    Date:
    conference 39969
    Status:
    Published
    DOI:
    link to the publication
  4. Prediction studies of cosmetics packages from aliphatic-aromatic copolyester and polylactide commercial blends (P38)

    Authors:
    Wanda Sikorska, Katarzyna Wolna-Stypka, Grazyna Adamus, Joanna Rydz, Marta Musiol
    Conference:
    Silesian Meetings on Polymer Materials, POLYMAT 2016 (year: 2016, pages: 41), Publisher: Centrum Materiałów Polimerowych i Węglowych PAN
    Date:
    conference 46931
    Status:
    Published
  5. Biodegradable polymeric system for controlled release of bioactive substances

    Authors:
    Iwona Kwiecień, Tomasz Bałakier, Janusz Jurczak, Iza Radecka, Marek Kowalczuk, Grażyna Adamus
    Conference:
    23rd annual meeting of the Bio-Environmental Polymer Society (year: 2015, pages: 61), Publisher: Bio-Environmental Polymer Society
    Date:
    conference 42289
    Status:
    Published
    DOI:
    link to the publication
  6. Novel synthetic approaches and opportunities for bioactive polyhydroxyalkanoates (Invited Lecture)

    Authors:
    G. Adamus, I. Kwiecień, M. Maksymiak, I. Radecka, M. Kowalczuk
    Conference:
    1st Annual ISBPPB's Conference & Exposition (year: 2014, pages: 46211), Publisher: International Society for Biomedical Polymers and Polymeric Biomaterials
    Date:
    conference July 9-12
    Status:
    Published

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