Projects funded by the NCN

Information on the principal investigator and host institution

Information of the project and the call

Keywords

Equipment

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The effect of strong Lewis bases on the structure of group 13 and 14 metal alkoxides and their catalytic activity in the polymerization of heterocyclic monomers

2012/07/E/ST5/02860

Keywords:

Main group metals metal alkoxides ring opening polymerization heterocyclic monomers

Descriptors:

  • ST5_14: Other related subjects
  • ST5_18:
  • ST5_21:

Panel:

ST5 - Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution :

Uniwersytet Warszawski, Centrum Nowych Technologii Uniwersytetu Warszawskiego

woj. mazowieckie

Other projects carried out by the institution 

Principal investigator (from the host institution):

dr Paweł Horeglad 

Number of co-investigators in the project: 4

Call: SONATA BIS 2 - announced on 2012-09-15

Amount awarded: 1 303 300 PLN

Project start date (Y-m-d): 2013-09-26

Project end date (Y-m-d): 2018-09-25

Project duration:: 60 months (the same as in the proposal)

Project status: Project settled

Equipment purchased [PL]

  1. Wyparka (cały zestaw z chillerem) (40 000 PLN)
  2. Dewar na ciekły azot (8 000 PLN)
  3. Kriostat (urządzenie chłodzące) (32 000 PLN)
  4. Pompy próżniowe z miernikiem próżni (4 szt.) (60 000 PLN)
  5. Sprzęt komputerowy: dwa komputery stacjonarne, dwa monitory, drukarka, skaner (15 000 PLN)
  6. waga laboratoryjna (12 000 PLN)
  7. Suszarka do szkła laboratoryjnego (8 000 PLN)
  8. Mieszadła magnetyczne (6 szt.) (16 800 PLN)
  9. licencje na oprogramowanie komputerowe.
  10. mieszadła magnetyczne.

Information in the final report

  • Publication in academic press/journals (7)
  1. Controlling the stereoselectivity of rac-LA polymerization by chiral recognition induced the formation of homochiral dimeric metal alkoxides
    Authors:
    P. Horeglad, M. Cybularczyk, A. Litwińska, A. M. Dąbrowska, M. Dranka, G. Z. Żukowska, M. Urbańczyk, M. Michalak
    Academic press:
    Polymer Chemistry (rok: 2016, tom: 7, strony: 2022-2036), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/C5PY02005K - link to the publication
  2. Probing M–CNHC bond and its effect on the synthesis, structure and reactivity of R2MOR(NHC) (M = Al, Ga, In) complexes
    Authors:
    Rafał Zaremba, Maciej Dranka, Bartosz Trzaskowski, Liliana Chęcińska, Paweł Horeglad
    Academic press:
    Organometallics (rok: 2018, tom: 37, strony: 4585-4598), Wydawca: ACS Publications
    Status:
    Published
    DOI:
    10.1021/acs.organomet.8b00570 - link to the publication
  3. Probing the effect of six membered N-heterocyclic carbene - 6-Mes - on the synthesis, structure and reactivity of Me2MOR(NHC) (M = Ga, In) complexes
    Authors:
    M. Cybularczyk-Cecotka, A. M. Dąbrowska, P. Guńka, P. Horeglad
    Academic press:
    Inorganics (rok: 2018, tom: 6, strony: 28), Wydawca: MDPI - Open Access Publishing
    Status:
    Published
    DOI:
    10.3390/inorganics6010028 - link to the publication
  4. Effect of In−CNHC bonds on the synthesis, structure, and reactivity of dialkylindium alkoxides: How indium compares to gallium
    Authors:
    M. Cybularczyk, M. Dranka, J. Zachara, P. Horeglad
    Academic press:
    Organometallics (rok: 2016, tom: 35, strony: 3311-3322), Wydawca: ACS Publications
    Status:
    Published
    DOI:
    10.1021/acs.organomet.6b00510 - link to the publication
  5. Polylactide conjugates of camptothecin with different drug release abilities
    Authors:
    E. Oledzka, P. Horeglad, Z. Gruszczyńska, A. Plichta, G. Nałęcz-Jawecki, M. Sobczak
    Academic press:
    Molecules (rok: 2014, tom: 19, strony: 19460-19470), Wydawca: MDPI - Open Access Publishing
    Status:
    Published
    DOI:
    10.3390/molecules191219460 - link to the publication
  6. Dialkylgallium alkoxides stabilized with N-heterocyclic carbenes – opportunities and limitations for the controlled and stereoselective polymerization of lactide.
    Authors:
    P. Horeglad, M. Cybularczyk, B. Trzaskowski, G, Z. Żukowska, M. Dranka. J. Zachara
    Academic press:
    Organometallics (rok: 2015, tom: 34, strony: 3480-3496), Wydawca: ACS Publications
    Status:
    Published
    DOI:
    10.1021/acs.organomet.5b00071 - link to the publication
  7. Towards NHC stabilized alkylgallium alkoxide/aryloxide cations - the advances, the limitations and the challenges
    Authors:
    A. M. Dąbrowska, A. Hurko, M. Dranka, V. Varga, M. Urbańczyk, P. Horeglad
    Academic press:
    Journal of Organometallic Chemistry (rok: 2017, tom: 840, strony: 63-69), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.jorganchem.2017.03.046 - link to the publication

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