Projects funded by the NCN

Information on the principal investigator and host institution

Information of the project and the call

Keywords

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Redox-cycling of metal-macrocycle complexes in the activation of small molecules (O2, NO) in homogeneous solutions: models, mechanisms and catalysis.

2012/05/B/ST5/00389

Keywords:

redox-cycling macrocyclic metal complexes small moleculles model systems mechanisms catalysis

Descriptors:

  • ST5_16:
  • ST5_14: Other related subjects
  • ST4_14: Catalysis

Panel:

ST5 - Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution :

Uniwersytet Jagielloński, Wydział Chemii

woj. małopolskie

Other projects carried out by the institution 

Principal investigator (from the host institution):

prof. Grażyna Stochel 

Number of co-investigators in the project: 14

Call: OPUS 3 - announced on 2012-03-15

Amount awarded: 942 800 PLN

Project start date (Y-m-d): 2013-02-13

Project end date (Y-m-d): 2016-02-12

Project duration:: 36 months (the same as in the proposal)

Project status: Project settled

Equipment purchased [PL]

  1. Światłowodowa sonda spektrofotometryczna z detektorem diode-array (125 000 PLN)
  2. Komputery do archiwizacji i przetwarzania danych wraz z oprogramowaniem (3 szt.) (33 000 PLN)
  3. Moduł lampy błyskowej do fluorymetru Fluorolog-3 z wyposażeniem do pomiarów fosforescencji (17 857 PLN)
  4. Zestaw światłowodowy do komory wysokociśnieniowej (26 691 PLN)

Information in the final report

  • Publication in academic press/journals (16)
  1. Mechanistic information on the nitrite controlled reduction of aquacob(III)alamin by ascorbate at physiological pH
    Authors:
    J. Polaczek, Ł. Orzeł, G. Stochel, R. van Eldik
    Academic press:
    J Biol Inorg Chem (rok: 2015, tom: 20, strony: 1069-1078), Wydawca: Springer
    Status:
    Published
    DOI:
    10.1007/s00775-015-1288-9 - link to the publication
  2. Spectroscopic and kinetic evidence for the crucial role of Compound 0 in the P450cam catalyzed hydroxylation of camphor by hydrogen peroxide
    Authors:
    A. Franke, R. van Eldik
    Academic press:
    Chem. Eur. J (rok: 2015, tom: 21, strony: 15201-15210), Wydawca: Wiley-VCH
    Status:
    Published
    DOI:
    10.1002/chem.201501886 - link to the publication
  3. Metal-assisted activation of nitric oxide - Mechanistic aspects of complex nitrosylation processes
    Authors:
    A. Franke, M. Oszajca, M. Brindell, G. Stochel, R. van Eldik
    Academic press:
    Adv. Inorg. Chem. (rok: 2015, tom: 67, strony: 171-241), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.005 - link to the publication
  4. Drug metabolism by cytochrome P450 enzymes: What distinguishes the pathways leading to substrate hydroxylation over desaturation?
    Authors:
    27.L. Ji, A.S. Faponle, M.G. Quesne, M.A. Sainna, J. Zhang, A. Franke, D. Kumar, R. van Eldik, W. Liu, S.P. de Visser
    Academic press:
    Chem. Eur. J. (rok: 2015, tom: 21, strony: 9083-9092), Wydawca: Wiley-VCH
    Status:
    Published
    DOI:
    10.1002/chem.201500329 - link to the publication
  5. Mechanistic Insight into Peroxo-Shunt Formation of Biomimetic Models for Compound II, their Reactivity toward Organic Substrates and the Influence of N-methylimidazole Axial Ligation
    Authors:
    M. Oszajca, A. Drzewiecka-Matuszek, Alicja Franke, D. Rutkowska-Żbik, M. Brindell, M. Witko, G.Stochel and R. van Eldik
    Academic press:
    Chem. Eur. J. (rok: 2014, tom: 20, strony: 2328-2343), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/chem.201303694 - link to the publication
  6. Recent advances in the investigations of NO activation on cobalt and manganese porphyrins: a brief review
    Authors:
    Ł. Orzeł, J. Polaczek, M. Procner
    Academic press:
    J. Coord. Chem (rok: 2015, tom: 68, strony: 2971–2989), Wydawca: Taylor & Francis Group
    Status:
    Published
    DOI:
    10.1080/00958972.2015.1068303 - link to the publication
  7. Redox cycling in the activation of peroxides by iron porphyrin and manganese complexes. 'Catching' catalytic active intermediates
    Authors:
    M. Oszjaca, A. Franke, M. Brindell, G. Stochel, R. van Eldik
    Academic press:
    Coordination Chemistry Review (rok: 2016, tom: 306, strony: 484-509), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.ccr.2015.01.013 - link to the publication
  8. Towards tuning PDT relevant photosensitizer properties: comparative study for the free and Zn2+ coordinated meso-tetrakis[2,6-difluoro-5-(N- methylsulfamylo)phenyl]porphyrin
    Authors:
    J.M. Dąbrowski, B. Pucelik, M.M. Pereira, L.G. Arnaut, G. Stochel
    Academic press:
    J. Coord. Chem (rok: 2015, tom: 68, strony: 3116-3134), Wydawca: Talyor & Francis Group
    Status:
    Published
    DOI:
    10.1080/00958972.2015.1073723 - link to the publication
  9. Combined experimental and theoretical study on the reactivity of compounds I and II in horseradish peroxidase biomimetics
    Authors:
    L. Ji, A. Franke, M. Brindell, M. Oszajca, A. Zahl, R. van Eldik
    Academic press:
    Chem. Eur. J. (rok: 2014, tom: 20, strony: 14437-14450), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/chem.201402347 - link to the publication
  10. Fine tuning of copper(II)–chlorophyll interactions in organic media. Metalation versus oxidation of the macrocycle
    Authors:
    Ł. Orzeł, B. Szmyd, D. Rutkowska-Żbik, L. Fiedor, R. van Eldik, G. Stochel
    Academic press:
    Dalton Trans. (rok: 2015, tom: 44, strony: 6012–6022), Wydawca: The Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/c4dt03809f - link to the publication
  11. New hybrid materials based on halogenated metalloporphyrins for enhanced visible light photocatalysis
    Authors:
    J. M. Dąbrowski, B. Pucelik, M. M. Pereira, L. G. Arnaut, W. Macyk, G. Stochel
    Academic press:
    RSC Advances (rok: 2015, tom: 5, strony: 93252-93261), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/c5ra19742b - link to the publication
  12. Spectroscopic and kinetic evidence for redox cycling, catalase and degradation activity of MnIII(TPPS) in a basic aqueous peroxide medium
    Authors:
    M. Procner, Ł. Orzeł, G. Stochel, R. van Eldik
    Academic press:
    Chem. Comm. (rok: 2016, tom: 52, strony: 5297-5300), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/C6CC01437B - link to the publication
  13. Temperature and pressure effects on C-H abstraction reactions involving compound I and II mimics in aqueous solution
    Authors:
    M. Oszajca, A. Franke, A. Drzewiecka-Matuszek, M. Brindell, G. Stochel and R. van Eldik
    Academic press:
    Inorganic Chemistry (rok: 2014, tom: 53, strony: 2848-2857), Wydawca: ACS Publications
    Status:
    Published
    DOI:
    10.1021/ic402567h - link to the publication
  14. The role of strong hypoxia in tumors after treatment in the outcome of bacteriochlorin-based photodynamic therapy
    Authors:
    M. Krzykawska-Serda, J. M. Dabrowski, L. G. Arnaut, M. Szczygiel, K. Urbanska, G. Stochel, M. Elas
    Academic press:
    Free Rad. Biol. Med (rok: 2014, tom: 73, strony: 239-251), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.freeradbiomed.2014.05.003 - link to the publication
  15. Mechanistic studies on versatile metal-assisted hydrogen peroxide activation processes for biomedical and environmental incentives
    Authors:
    M. Oszajca, M. Brindell, Ł. Orzeł, J. M. Dąbrowski, K. Śpiewak, P.Łabuz, M. Pacia, A. Stochel-Gaudyn, W. Macyk, R. van Eldik, G. Stochel
    Academic press:
    Coordination Chemistry Review (rok: 2016, tom: brak, strony: brak), Wydawca: Elsevier
    Status:
    Accepted for publication
    DOI:
    10.1016/j.ccr.2016.05.013 - link to the publication
  16. Factors controlling the formation of metallochlorophylls in organic media
    Authors:
    Ł. Orzeł, J. Waś, A. Kania, A. Susz, D. Rutkowska-Żbik, J. Staroń, M. Witko, G. Stochel, L. Fiedor
    Academic press:
    Inorg. Chem. (rok: 2016, ), Wydawca: ACS Publications
    Status:
    Submitted
    DOI:
    brak - link to the publication

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